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Simple ethers of 2-hydroxyhexene-5-yne-3-yl-2-cyclopentadienylmanganese tricarbonyl

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    2-Hydroxyhexene-5-yne-3-yl-2-cyclopentadienylmanganese tricarbonyl does not isomerize in alcohol medium in the presence of catalysts HgSO4 or HgO·(C2H5)2O · BF3, but forms simple ethers.

  2. 2.

    2-Methoxy-, 2-ethoxy-, 2-propoxy-, 2-butoxy-, and 2-allyloxyhexene-5-yne-3-yl -2-cyclopentadienyl-manganese tricarbonyls were produced and characterized.

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Literature cited

  1. A. N. Nesmeyanov, K. N. Anisimov, N. E. Kolobova, and G. K. Magomedov, Izv. AN SSSR. Otd. Khim. N., 2072 (1962).

  2. A. N. Elizarova and I. N. Nazarov, Izv. AN SSSR. Otd. Khim. N., 223 (1940).

  3. L. J. Bellamy, Infrared Spectra of Complex Molecules [Russian Translation], Foreign Literature Press, Moscow (1963) p. 156.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences, USSR

    K. N. Anisimov, N. E. Kolobova, G. K. Magomedov & G. D. Dvoryantseva

Authors
  1. K. N. Anisimov
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  2. N. E. Kolobova
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  3. G. K. Magomedov
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  4. G. D. Dvoryantseva
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1320–1322, July, 1964

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Anisimov, K.N., Kolobova, N.E., Magomedov, G.K. et al. Simple ethers of 2-hydroxyhexene-5-yne-3-yl-2-cyclopentadienylmanganese tricarbonyl. Russ Chem Bull 13, 1225–1227 (1964). https://doi.org/10.1007/BF00863137

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  • DOI: https://doi.org/10.1007/BF00863137

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