Conclusions
The addition of methanol to 5-methylhexadiyne-1,3-ol-5 (II) was studied under acid and alkaline conditions, and the structure of the synthetically interesting derivatives of ethynyl vinyl ether and acetylenicγ-ketols thereby formed was demonstrated.
Literature cited
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N. A. Milas and J. T. Nolan, J. Amer. Chem. Soc.,80, 5826 (1958).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1318–1319, July, 1964
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Gusev, B.P., Kucherov, V.F. On the character of the addition of alcohols to diacetylenic carbinols. Russ Chem Bull 13, 1222–1224 (1964). https://doi.org/10.1007/BF00863136
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DOI: https://doi.org/10.1007/BF00863136