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Telomerization of dimethylcyclosiloxanes. Communication 6. Reactions of hexamethylcyclotrisiloxane with dichloromethylsilane, dichloromethylvinylsilane, and dichloromethylphenylsilane

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    It was shown that in telomerization with hexamethylcyclotrisiloxane organodichlorosilanes fall in the following order of diminishing activity: CH3HSiCl2> CH2=CHCH3SiCl2>C6H5CH3SiCl3

  2. 2.

    A preparative method was developed for the synthesis of bifunctional oligomers, and with its aid seven new compounds were synthesized.

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Literature cited

  1. K. A. Andrianov and V. V. Severnyi, Dokl. AN SSSR,134, No. 6 (1960).

  2. K. A. Andrianov and V. V. Severnyi, Izv. AN SSSR. Otd. khim. n., 1783 (1961).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences, USSR

    K. A. Andrianov & V. V. Severnyi

Authors
  1. K. A. Andrianov
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  2. V. V. Severnyi
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1268–1271, July, 1964

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Andrianov, K.A., Severnyi, V.V. Telomerization of dimethylcyclosiloxanes. Communication 6. Reactions of hexamethylcyclotrisiloxane with dichloromethylsilane, dichloromethylvinylsilane, and dichloromethylphenylsilane. Russ Chem Bull 13, 1174–1177 (1964). https://doi.org/10.1007/BF00863124

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  • DOI: https://doi.org/10.1007/BF00863124

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