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Chemistry of acetals. Communication 15. Selective hydrolysis of 3-ethoxy-4-hexenal diethyl acetal and some reactions of 3-ethoxy-4-hexenal

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A method was developed for the hydrolysis of 3-ethoxy-4-hexenal diethyl acetal to 3-ethoxy-4-hexenal.

  2. 2.

    A study was made of the reactions of 3-ethoxy-4-hexenal with ethyl (triphenylphosphoranylidene)acetate and primary and secondary nitro compounds, and also of the hydroxylation of 3-ethoxy-4-hexenal diethyl acetal to the corresponding ethoxy dihydroxy C6 acetal.

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Literature cited

  1. I. N. Nazarov, I. I. Nazarova, and I. V. Torgov, Dokl. AN SSSR,122, 82 (1958).

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  2. V. F. Kucherov, B. G. Kovalev, I. I. Nazarova, and L. A. Yanovskaya, Izv. AN SSSR. Otd. khim. n.,1960, 1512.

  3. V. F. Kucherov and B. A. Rudenko, Dokl. AN SSSR, in the press.

  4. É. A. Mistryukov. Collect. czech. chem. commun.,26, 2071 (1961).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    I. I. Nazarova, L. A. Yanovskaya & V. F. Kucherov

Authors
  1. I. I. Nazarova
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  2. L. A. Yanovskaya
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  3. V. F. Kucherov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1245–1249, July, 1964

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Nazarova, I.I., Yanovskaya, L.A. & Kucherov, V.F. Chemistry of acetals. Communication 15. Selective hydrolysis of 3-ethoxy-4-hexenal diethyl acetal and some reactions of 3-ethoxy-4-hexenal. Russ Chem Bull 13, 1154–1157 (1964). https://doi.org/10.1007/BF00863120

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  • DOI: https://doi.org/10.1007/BF00863120

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