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Trialkenyldialkyl- and trialkenyldiarylantimonys

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Diphenyltri-cis-propenylantimony, diphenyltri-trans-propenylantimony, and triisopropenyldiphenylantimony were synthesized from the corresponding isomeric trialkenyldibromoantimonys and phenylmagnesium bromide.

  2. 2.

    An investigation was made of the decomposition by halogens of the trialkyldiethyl- and trialkenyl-diphenylantimonys prepared, and it was shown that, except in the case of diethyltri-trans-propenylantimony, in all the cases investigated alkenyl groups were split off first, not ethyl or phenyl groups.

  3. 3.

    The infrared absorption spectra were investigated of the geometric isomers isolated.

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Literature cited

  1. A. N. Nesmeyanov, A. E. Borisov and N. V. Novikova, Izv. AN SSSR. Otd. khim. n.1961, 730.

  2. A. N. Nesmeyanov, A. E. Borisov and N. V. Novikova, Izv. AN SSSR. Otd. khim. n.1961, 614.

  3. A. N. Nesmeyanov, A. E. Borisov, I. S. Savel'eva and N. V. Kruglova, Izv. AN SSSR. Otd. khim. n.1961, 726; A. N. Nesmeyanov, A. E. Borisov and I. S. Savel'eva, Izv. AN SSSR. Otd. khim. n.1961, 2241.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences, USSR

    A. N. Nesmeyanov, A. E. Borisov & N. V. Novikova

Authors
  1. A. N. Nesmeyanov
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  2. A. E. Borisov
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  3. N. V. Novikova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1197–1202, July, 1964

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Nesmeyanov, A.N., Borisov, A.E. & Novikova, N.V. Trialkenyldialkyl- and trialkenyldiarylantimonys. Russ Chem Bull 13, 1112–1115 (1964). https://doi.org/10.1007/BF00863110

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  • DOI: https://doi.org/10.1007/BF00863110

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