Skip to main content
Log in

Preparation and reactivity of metal-containing monomers. 23. Transition metal complexes of methacryloylacetone

  • Organic Chemistry
  • Methods Of Synthesis
  • Published:
Bulletin of the Russian Academy of Sciences, Division of chemical science Aims and scope

Abstract

The Cu(II), Ni(II), Co(II), Mn(II), Fe(III), and Cr(III) complexes of methacryloylacetone have been obtained. Magnetochemical, IR, and electronic spectroscopic studies have shown these to contain the copper ion in a square planar configuration, and the other metals in the octahedral configuration. The complexes have similar steric structures both in the crystal and in solution.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. Structure, Properties, and Uses of Metal β-Diketonates [in Russian], Nauka, Moscow (1978).

  2. Topics in the Chemistry and Uses of Metal β-Diketonates [in Russian], Nauka, Moscow (1982).

  3. A. D. Pomogailo and V. S. Savost'yanov,Metal-Containing Monomers and Polymers Derived Therefrom [in Russian], Khimiya, Moscow (1988).

    Google Scholar 

  4. G. Manacke and E. Graudenz,Makromol. Chem.,170, 51 (1973).

    Google Scholar 

  5. Y. Okamoto, S. S. Wang, K. J. Shu, E. Banks, B. Garetz, and E. K. Murphy,Metal-Containing Polymer Systems, Plenum Press, New York (1985), p. 425.

    Google Scholar 

  6. R. G. Degeiso, L. G. Donaruma, and E. A. Tomic,J. Polym. Sci.,7, 1515 (1963).

    Google Scholar 

  7. I. S. Voloshanovskii, T. J. Movchan, and L. Yu. Pakarina,Nontraditional Methods of Polymer Synthesis, International School-Seminar for Young Scientists (1990), p. 164.

  8. I. E. Uflyand, I. A. Il'chenko, A. G. Starikov, V. N. Sheinker, and A. D. Pomogailo,Izv. Akad. Nauk, Ser. Khim., No. 1, 451 (1990).

  9. I. E. Uflyand, I. A. Il'chenko, V. N. Sheinker, and A. V. Bulatov,React. Polym.,13, No. 1, 41 (1991).

    Google Scholar 

  10. W. S. Fernelius and B. F. Bryant,Inorg. Synth., No. 5, 105 (1957).

  11. K. Nakamoto,Infrared Spectra of Inorganic and Coordination Compounds, Wiley, New York (1963).

    Google Scholar 

  12. V. T. Kaminskii and Yu. V. Rakitin,An Introduction to Magnetochemistry [in Russian], Nauka, Moscow (1980).

    Google Scholar 

  13. R. Drago,Physical Methods in Inorganic Chemistry, Reinhold, New York (1965).

    Google Scholar 

  14. A. Liver,The Electronic Spectroscopy of Inorganic Compounds [Russian translation], Vol. 2, Mir, Moscow (1987), p. 400.

    Google Scholar 

  15. M. A. Hitchman and R. L. Belford,Inorg. Chem.,10, 984 (1972).

    Google Scholar 

  16. T. I. Movchan, I. S. Voloshanovskii, and L. Yu. Pakarina, “A method of preparation of unsaturated β-diketones,” USSR Inventor's Certificate No. 4,737,387/23-04. Accepted October 19, 1990.

  17. V. P. Kurbatov, A. V. Khokhlov, A. D. Garnovskii, et al.,Koordinats. Khim.,5, 351 (1971).

    Google Scholar 

Download references

Authors

Additional information

Institute of Chemical Physics, Russian Academy of Sciences, 142432 Chernogolovka. I. I. Mechnikov Odessa State University. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 3, pp. 694–699, March, 1992.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Movchan, T.I., Starikov, A.G., Ivleva, I.N. et al. Preparation and reactivity of metal-containing monomers. 23. Transition metal complexes of methacryloylacetone. Russ Chem Bull 41, 545–548 (1992). https://doi.org/10.1007/BF00863082

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00863082

Keywords

Navigation