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1,1,4,4-Tetranitrobutane-2,3-diol and its derivatives. 3. Synthesis of 1,4-dichloro- and 1,4-dibromo-1,1,4,4-tetranitrobutane-2,3-diol dinitrates and their crystalline structure

  • Organic Chemistry
  • Methods Of Synthesis
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Bulletin of the Russian Academy of Sciences, Division of chemical science Aims and scope

Abstract

1,4-Dichloro- (1) and 1,4-dibromo-1,1,4,4-tetranitrobutane-2,3-diol dinitrates (2) were synthesized by nitration of the corresponding diols with a mixture of trifluoroacetic anhydride and nitric acid. The x-ray diffraction investigations of 1 and 2 that have been carried out showed the influence of the intramolecular interactions of the nitro and nitrate groups on the packing of the molecules in the crystal.

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Authors
  1. B. S. Fedorov
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  2. N. I. Golovina
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  3. V. V. Arakcheeva
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  4. L. S. Barinova
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  5. R. F. Trofimova
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  6. P. V. Galkin
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  7. L. O. Atovmyan
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Additional information

Institute of Chemical Physics, Russian Academy of Sciences, 142432 Chernogolovka. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 3, pp. 664–671, March, 1992.

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Fedorov, B.S., Golovina, N.I., Arakcheeva, V.V. et al. 1,1,4,4-Tetranitrobutane-2,3-diol and its derivatives. 3. Synthesis of 1,4-dichloro- and 1,4-dibromo-1,1,4,4-tetranitrobutane-2,3-diol dinitrates and their crystalline structure. Russ Chem Bull 41, 522–527 (1992). https://doi.org/10.1007/BF00863076

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  • DOI: https://doi.org/10.1007/BF00863076

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