Skip to main content
SpringerLink
Log in

13C and1H NMR study of molecular motion in the deoxycholic acid-ferrocene solid inclusion compound

  • Physical Chemistry
  • Structure And Physicochemical Properties Of Molecules
  • Published:
Bulletin of the Russian Academy of Sciences, Division of chemical science Aims and scope

Abstract

Using solid-state13C NMR spectroscopy and also measurements of proton spin-lattice relaxation times T 1 and second moments M 2 , we have investigated molecular motion in solid inclusion compounds of deoxycholic acid with ferrocene in the interval 100–400 K. We have identified various dynamic processes occurring with participation of molecules of the matrix and the included molecules. We have shown that in addition to rapid reorientations of the cyclopentadienyl rings, the ferrocene molecules undergo 180° jumps about the C 2 axis. We have determined the parameters for all the molecular motions. We discuss the conformational state of the included molecules.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. K. Miki, N. Kasai, H. Tsutsumi, et al.,J. Chem. Soc. Chem. Commun., No. 8, 545 (1987).

  2. Z. Narankiewicz, A. L. Blumenfeld, V. L. Bondareva, et al.,J. Inclus. Phenom.,11, 233 (1991).

    Google Scholar 

  3. S. J. Heyes and Ch. M. Dobson,Magn. Res. Chem.,28, 837 (1990).

    Google Scholar 

  4. J. G. Jones, S. Schwarzbaum, L. Lessinger, and B. W. Low,Acta Crystallogr.,B-38, 1207 (1982).

    Google Scholar 

  5. J. Herzfeld and A. E. Berger,J. Chem. Phys.,73, No. 12, 6021 (1980).

    Google Scholar 

  6. M. M. Maricq and J. S. Waugh,J. Chem. Phys.,70, No. 7, 3300 (1979).

    Google Scholar 

  7. A. Kubo, R. Ikeda, and D. Nakamura,J. Chem. Soc. Faraday Trans. II,82, 1543 (1986).

    Google Scholar 

  8. J. S. Waugh and É. I. Fedin,Fiz. Tverd. Tela,4, 2233 (1962).

    Google Scholar 

  9. D. Suwelack, W. P. Rothwell, and J. S. Waugh,J. Chem. Phys.,73, No. 6, 2559 (1980).

    Google Scholar 

  10. J. M. Dereppe,J. Chem. Phys.,58, 1254 (1973).

    Google Scholar 

  11. M. Polak,J. Chem. Phys.,65, 2785 (1976).

    Google Scholar 

Download references

Authors
  1. Z. Narankevich
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. L. Blyumenfel'd
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. I. Sokolov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

A. N. Nesmeyanov Institute of Heteroorganic Compounds, Russian Academy of Sciences, Moscow 117813. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 3, pp. 586–593, March, 1992.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Narankevich, Z., Blyumenfel'd, A.L. & Sokolov, V.I. 13C and1H NMR study of molecular motion in the deoxycholic acid-ferrocene solid inclusion compound. Russ Chem Bull 41, 462–467 (1992). https://doi.org/10.1007/BF00863064

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00863064

Keywords

Search

Navigation