Abstract
The structurization activity of cobalt, nickel, and copper acrylates in gelatin layers under the influence of monochromatic laser radiation with a wavelength of 633 nm has been studied. It has been established with the aid of IR and electronic spectroscopy that the complexation of the acrylate salts of Co(II), Ni(II), and Cu(II) with gelatin is accomplished by means of the OH groups of the hydroxyproline residues. It has been shown that the photosensitivity and density of the photographic layers are determined by the nature of the transition metal and increase along the series Co(II) < Ni(II) < Cu(II). Thin phase holograms with a diffraction efficiency (η) equal to 33% have been obtained.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
A. L. Kartuzhanskii, B. T. Plachenov, and O. P. Studzinskii,Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol.,32, No. 2, 3 (1990).
O. V. Mikhailov and V. K. Polovnyak,Koordinats. Khim.,15, No. 2, 147 (1989).
S. I. Peredvereva, V. M. Kozenkov, and L. P. Kisilitsa,Photopolymers for Holography. Silver-Free and Unusual Media for Holography [in Russian], Nauka, Moscow (1978), p. 51.
G. I. Dzhardimalieva, A. D. Pomogailo, V. I. Ponomarev, et al.,Izv. Akad. Nauk, Ser. Khim., No. 7, 1525 (1988).
R. J. Collier, C. B. Burckhardt, and H. L. Lawrence,Optical Holography, Academic Press, New York (1971).
H. R. Brown, "Flory-Huggins-Rehner theory and the swelling of semicrystalline polymers by organic fluids,"Polym. Phys. Ed.,16, No. 10, 1887 (1978).
G. M. Kline (ed.),Analytical Chemistry of Polymers, Interscience, New York (1959–1962).
A. Veis,The Macromolecular Chemistry of Gelatin, Academic Press, New York (1964).
R. M. Silverstein, G. C. Bassler, and T. C. Morrill,Spectrometric Identification of Organic Compounds, 3rd edn., Wiley, New York (1974).
Yu. N. Chirgadze,Infrared Spectra and Structures of Polypeptides and Proteins [in Russian], Nauka, Moscow (1965).
I. I. Levkoev,Organic Compounds in Photographic Processes [in Russian], Nauka, Moscow (1982).
Additional information
Institute of Chemical Physics, Russian Academy of Sciences, Chernogolovka 142432. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 3, pp. 576–581, March, 1992.
Rights and permissions
About this article
Cite this article
Botsman, A.V., Fedorova, L.N., Vasil'chenko, A.I. et al. Synthesis and reactivity of metal-containing monomers. 20. Photochemical structurization of gelatin mixtures with the participation of transition metal acrylates. Russ Chem Bull 41, 454–458 (1992). https://doi.org/10.1007/BF00863062
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00863062