Skip to main content
SpringerLink
Log in

Laser photolysis study of chloranil triplet exciplexes with stilbene

  • Physical Chemistry
  • Thermodynamics
  • Published:
Bulletin of the Russian Academy of Sciences, Division of chemical science Aims and scope

Abstract

Absorption spectra and decay kinetics of the polar triplet exciplexes (contact radical-ion pairs) formed during quenching of the chloranil triplet state by trans- or cis-stilbenes in benzene with added acetonitrile and methanol, have been studied by laser flash photolysis. The exciplexes include cation-radicals of stilbene dimers, which are deactivated by reverse electron transfer within 10–50 nsec. The dynamics of the intercombination electron transfer and the exciplex dissociation into ion-radicals were determined. The isomerization of stilbene via triplet exciplex formation was not observed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. P. P. Levin and V. A. Kuz'min,Usp. Khim.,56, 527 (1987).

    Google Scholar 

  2. P. P. Levin and V. A. Kuz'min,Izv. Akad. Nauk SSSR, Ser. Khim., No. 6, 1435 (1986).

    Google Scholar 

  3. H. Kobashi, M. Funabashi, T. Kondo, et al.,Bull. Chem. Soc. Jpn.,57, 3557 (1984).

    Google Scholar 

  4. V. A. Kuz'min and P. P. Levin,Izv. Akad. Nauk SSSR, Ser. Khim., No. 3, 515 (1988).

    Google Scholar 

  5. H. Kobashi, H. Sato, and H. Shizuka,Bull. Chem. Soc. Jpn.,63, 1441 (1990).

    Google Scholar 

  6. I. G. Jones, W. A. Haney, and X. T. Phan,J. Am. Chem. Soc.,110, 1922 (1988).

    Google Scholar 

  7. P. P. Levin and V. A. Kuz'min,Izv. Akad. Nauk SSSR, Ser. Khim., No. 8, 1901 (1987).

  8. A. I. Kruppa, O. I. Mikhailovskaya, and T. V. Leshina,Chem. Phys. Lett.,147, 65 (1988).

    Google Scholar 

  9. Y. Kuriyama, T. Arai, H. Sakuragi, and K. Tokumaru,Chem. Phys. Lett.,173, 253 (1990).

    Google Scholar 

  10. T. Shida and W. H. Hamill,J. Chem. Phys.,44, 2375 (1966).

    Google Scholar 

  11. A. Kira, S. Arai, and M. Imamura,J. Phys. Chem.,76, 1119 (1972).

    Google Scholar 

  12. R. Akaba, H. Sakuragi, and K. Tokumaru,Chem. Phys. Lett.,174, 80 (1990).

    Google Scholar 

  13. P. P. Levin, P. F. Pluzhnikov, and V. A. Kuz'min,Khim. Fiz.,8, 752 (1989).

    Google Scholar 

  14. F. D. Lewis, A. M. Bedell, R. E. Dykstra, et al.,J. Am. Chem. Soc.,112, 8055 (1990).

    Google Scholar 

Download references

Authors
  1. P. P. Levin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. A. Kuz'min
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow 117977. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 3, pp. 572–576, March, 1992.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Levin, P.P., Kuz'min, V.A. Laser photolysis study of chloranil triplet exciplexes with stilbene. Russ Chem Bull 41, 451–453 (1992). https://doi.org/10.1007/BF00863061

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00863061

Keywords

Search

Navigation