Oxidation of secondary aromatic amines by organic hydroperoxides, ozone, and hydrogen peroxide

  • A. B. Shapiro
  • A. V. Osipova
  • L. A. Skripko
  • S. D. Razumovskii
  • E. G. Rozantsev
Brief Communications

Conclusions

  1. 1.

    The stable di-(4-dimethylneopentylmethylphenyl)nitroxyl radical was obtained by the action of tert-butyl hydroperoxide, as well as of ozone, on di-(4-dimethylneopentylmethylphenyl)amine.

     
  2. 2.

    The corresponding pure nitroxyl radicals were obtained by the catalytic oxidation of the 4,4′-dimethoxy- and 4,4′-diethoxydiphenylamines with hydrogen peroxide in the presence of sodium tungstate.

     

Keywords

Oxidation Hydrogen Sodium Hydrogen Peroxide Ozone 

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Literature cited

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Copyright information

© Consultants Bureau 1971

Authors and Affiliations

  • A. B. Shapiro
    • 1
  • A. V. Osipova
    • 1
  • L. A. Skripko
    • 1
  • S. D. Razumovskii
    • 1
  • E. G. Rozantsev
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRUSSR

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