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Reaction of bis- (hydroxymethyl) phosphinic acid with phosphorus pentachloride

  • Yu. V. Nazarov
  • A. A. Muslinkin
  • V. F. Zheltukhin
Brief Communications

Conclusions

  1. 1.

    A study was made of the reaction of bis-(hydroxymethyl)phosphinic acid with PC15 in phosphorus oxychloride medium in the temperature range from 60 to 100°.

     
  2. 2.

    On the basis of the experimental data a reaction mechanism was proposed, which explains the formation of the di(acid chloride) of chloromethylphosphonic acid and methyl chloride.

     

Keywords

Methyl Chloride Experimental Data Phosphorus Reaction Mechanism 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    B. E. Ivanov, V. G. Trutnev, and I. M. Shermergorn, USSR Patent 187779 (1965); Byull. Izobr., No. 21, 39 (1966).Google Scholar
  2. 2.
    B. E. Ivanov, A. R. Panteleeva, R. R. Shagidullin, and I. M. Shermergorn, Zh. Obshch. Khim.,37, 1856 (1967).Google Scholar
  3. 3.
    A. A. Muslinkin, Yu. V. Nazarov, and S. P. Dyatlov, Data of Scientific Conference of A. E. Arbuzov Institute of Organic and Physical Chemistry of the Academy of Sciences of the USSR [in Russian], Kazan (1970), p. 40.Google Scholar
  4. 4.
    T. I. Karpova and A. A. Muslinkin, USSR Patent 245098 (1968); Byull. Izobr., No. 19, 29 (1969).Google Scholar
  5. 5.
    A. W. Frank, Can. J. Chem.,46, No. 22, 3573 (1968); Ref. Zh. Khim., 14B854 (1969).Google Scholar

Copyright information

© Consultants Bureau 1972

Authors and Affiliations

  • Yu. V. Nazarov
    • 1
  • A. A. Muslinkin
    • 1
  • V. F. Zheltukhin
    • 1
  1. 1.A. E. Arbuzov Institute of Organic and Physical ChemistryAcademy of Sciences of the USSRUSSR

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