Mechanism of the reaction of chain propagation in processes of liquid-phase oxidation in the presence of copper stearate

  • B. G. Bal'kov
  • I. P. Skibida
Physical Chemistry
  • 18 Downloads

Conclusions

  1. 1.

    The rates of formation and consumption of alcohols, ketones, and acids in the oxidation of n-decane catalyzed by copper stearate were measured. A comparison of the rates of formation of the oxidation products with the rate of consumption of hydroperoxide indicated that the bulk of the alcohols, ketones, and acids are formed directly from the peroxide radical, bypassing the state of hydroperoxide formation.

     
  2. 2.

    In the catalysis of CuSt2, part of the peroxide radicals are converted to oxidation products with cleavage of the C-C bond before the stage of acid formation.

     

Keywords

Oxidation Copper Alcohol Peroxide Catalysis 

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Copyright information

© Consultants Bureau 1972

Authors and Affiliations

  • B. G. Bal'kov
    • 1
  • I. P. Skibida
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRUSSR

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