Skip to main content
Log in

Influence of the intramolecular field on the nuclear quadrupole resonance frequencies in a series of organic chloro-derivatives

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The dependences of the frequency shift in the NQR spectra of Cl35 and the σ* substituent constants on the electrostatic effect of substituents were discussed; some conclusions on the three-dimensional structure of the molecules and the mechanism of induction were drawn on the basis of them.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. A. N. Vereshchagin, S. G. Vul'fson, Teoret. i Éksperim. Khim.,1, 305 (1965).

    Google Scholar 

  2. A. N. Vereshchagin and S. G. Vul'fson, Izv. Akad. Nauk SSSR, Ser. Khim., 1226 (1967).

  3. S. G. Vul'fson, I. P. Biryukov, and A. N. Vereshchagin, Izv. Akad. Nauk SSSR, Ser. Khim., 1008 (1970).

  4. B. A. Arbuzov, S. G. Vul'fson, I. A. Safin, I. P. Biryukov, and A. N. Vereshchagin, Izv. Akad. Nauk SSSR, Ser. Khim., 1234 (1970).

  5. J. I. Musher, J. Chem. Phys.,37, 2372 (1962).

    Google Scholar 

  6. H. Shimizu and M. Shimizu, J. Chem. Phys.,40, 2068 (1964).

    Google Scholar 

  7. S. Scrocco, P. Bucci, and M. Maestro, J. Chim. Phys.,56, 623 (1959).

    Google Scholar 

  8. Y. Morino, I. Miyagawa, T. Chiba, and T. Shimozawa, J. Chem. Phys.,25, 185 (1956).

    Google Scholar 

  9. E. N. Tsvetkov, G. K. Semin, D. I. Lobanov, and M. I. Kabachnik, Teoret. i Éksperim. Khim.,4, 452 (1968).

    Google Scholar 

  10. G. K. Semin and E. V. Bryuchova, Chem. Comm., 605 (1968).

  11. G. K. Semin, L. S. Kobrina, and G. G. Yakobson, Izv. Akad. Nauk SSSR, Ser. Khim., No. 9 (4), 84 (1968).

    Google Scholar 

  12. E. N. Tsvetkov, G. K. Semin, D. I. Lobanov, and M. I. Kabachnik, Tetrahedron Letters, 2933 (1967).

  13. G. K. Semin, Dokl. Akad. Nauk SSSR,158, 1169 (1964).

    Google Scholar 

  14. I. P. Biryukov, M. G. Voronkov, and I. A. Safin, Tables of Nuclear Quadrupole Resonance Frequencies [in Russian], Khimiya (1968).

  15. E. A. C. Lucken, J. Chem. Soc., 2954 (1959).

  16. L. Meyer, Z. Phys. Chem.,8, 27 (1930).

    Google Scholar 

  17. O. A. Osipov, V. I. Minkin, and Yu. A. Zhdanov, Handbook of Dipole Moments [in Russian], Vysshaya Shkola (1965).

  18. T. A. Bubshkina, V. I. Pobas, and T. K. Semin, in: Radiospectroscopy of the Solid State [in Russian], Atomizdat (1967), p. 221.

  19. Landolt-Bornstein, Zahlenwerte und Funktionen, Springer,1, 3, 142073 (1951).

  20. V. S. Grechishkin and G. B. Soifer, in: Radiospectroscopy of the Solid State [in Russian], Atomizdat (1967), p. 242.

  21. Yu. K. Maksyutin, E. V. Bryukhova, G. K. Semin, and E. N. Gur'yanova, Izv. Akad. Nauk SSSR, Ser. Khim., 2658 (1968).

  22. É. A. Kravchenko, Yu. K. Maksyutin, E. N. Gur'yanova, and G. K. Semin, Izv. Akad. Nauk SSSR, Ser. Khim., 1271 (1968).

  23. G. K. Semin and T. A. Babushkina, Teoret. i Éksperim. Khim.,4, 835 (1968).

    Google Scholar 

  24. J. F. Harrison, J. Chem. Phys.,48, 2379 (1968).

    Google Scholar 

  25. Yu. A. Zhdanov and V. I. Minkin, Correlation Analysis in Organic Chemistry [in Russian], Izd-vo Rostovsk. Un-ta (1966), p. 312.

  26. V. A. Pal'm, Fundamentals of the Quantitative Theory of Organic Reactions [in Russian], Khimiya (1967), p. 98.

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2473–2478, November, 1970.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Vul'fson, S.G., Vereshchagin, A.N. Influence of the intramolecular field on the nuclear quadrupole resonance frequencies in a series of organic chloro-derivatives. Russ Chem Bull 19, 2326–2330 (1970). https://doi.org/10.1007/BF00859069

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00859069

Keywords

Navigation