Thermal decomposition of cyclic peroxydiacids

  • G. I. Nikishin
  • E. K. Starostin
  • B. A. Golovin
  • E. D. Lubuzh
Physical Chemistry


  1. 1.

    New cyclic peroxydiacids were synthesized: peroxydi-cis-hexahydrophthalic, peroxydi-cis-Δ4-tetrahydrophthalic, and peroxydi-cis-endomethylene-Δ4-tetrahydrophthalic.

  2. 2.

    The thermal decomposition of peroxydiacids in acetic acid obeys a first-order equation with respect to the peroxide. As a result of the decomposition of the peroxydiacids, anhydrides are formed. A mechanism was proposed for their formation by cyclization of acyloxy radicals.



Acetic Peroxide Acetic Acid Thermal Decomposition Anhydride 
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Copyright information

© Consultants Bureau, a division of Plenum Publishing Corporation 1972

Authors and Affiliations

  • G. I. Nikishin
    • 1
  • E. K. Starostin
    • 1
  • B. A. Golovin
    • 1
  • E. D. Lubuzh
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRUSSR

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