Advertisement

Thermal decomposition of cyclic peroxydiacids

  • G. I. Nikishin
  • E. K. Starostin
  • B. A. Golovin
  • E. D. Lubuzh
Physical Chemistry

Conclusions

  1. 1.

    New cyclic peroxydiacids were synthesized: peroxydi-cis-hexahydrophthalic, peroxydi-cis-Δ4-tetrahydrophthalic, and peroxydi-cis-endomethylene-Δ4-tetrahydrophthalic.

     
  2. 2.

    The thermal decomposition of peroxydiacids in acetic acid obeys a first-order equation with respect to the peroxide. As a result of the decomposition of the peroxydiacids, anhydrides are formed. A mechanism was proposed for their formation by cyclization of acyloxy radicals.

     

Keywords

Acetic Peroxide Acetic Acid Thermal Decomposition Anhydride 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    R. N. Hermans and J. van Eyk, J. Polymer,1, 407 (1946).Google Scholar
  2. 2.
    C. G. Swain, L. J. Schaad, and A. J. Kresge, J. Amer. Chem. Soc.,80, 5313 (1958).Google Scholar
  3. 3.
    J. R. Leffler, R. D. Faulkner, and C. C. Petroponlons, J. Amer. Chem. Soc.,80, 5435 (1958).Google Scholar
  4. 4.
    H. Hart and D. P. Wyman, J. Amer. Chem. Soc.,81, 4891 (1959).Google Scholar
  5. 5.
    F. D. Greene, H. P. Stein, C. C. Chu, and F. M. Vane, J. Amer. Chem. Soc.,86, 2081 (1964).Google Scholar
  6. 6.
    F. D. Greene, C. C. Chu, and J. Walid, J. Organ. Chem.,29, 1285 (1964).Google Scholar
  7. 7.
    H. Hart and F. J. Chloupek, J. Amer. Chem. Soc.,85, 1155 (1963).Google Scholar
  8. 8.
    G. I. Nikishin, A. T. Koritskii, and E. K. Starostin, Izv. Akad. Nauk SSSR, Ser. Khim., 586 (1970).Google Scholar
  9. 9.
    G. I. Nikishin, E. K. Starostin, and B. A. Golovin, Izv. Akad. Nauk SSSR, Ser. Khim., 1209 (1970).Google Scholar
  10. 10.
    G. I. Nikishin, E. K. Starostin, and B. A. Golovin, Izv. Akad. Nauk SSSR, Ser. Khim., 946 (1971).Google Scholar
  11. 11.
    A. Bayer and V. Villiger, Ber.,34, 762 (1901).Google Scholar
  12. 12.
    V. Karnozhitskii, Organic Peroxides [Russian translation], IL (1961), p. 66.Google Scholar
  13. 13.
    New Methods of Preparative Organic Chemistry [Russian translation], IL (1950), p. 125.Google Scholar
  14. 14.
    F. Critchfield, Analysis of the Basic Functional Groups in Organic Compounds [Russian translation], Mir (1965), p. 185.Google Scholar
  15. 15.
    L. B. Bellamy, Infrared Spectra of Complex Molecules [Russian translation], IL (1963), p. 184.Google Scholar

Copyright information

© Consultants Bureau, a division of Plenum Publishing Corporation 1972

Authors and Affiliations

  • G. I. Nikishin
    • 1
  • E. K. Starostin
    • 1
  • B. A. Golovin
    • 1
  • E. D. Lubuzh
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRUSSR

Personalised recommendations