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Thermal decomposition of cyclic peroxydiacids

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    New cyclic peroxydiacids were synthesized: peroxydi-cis-hexahydrophthalic, peroxydi-cis-Δ4-tetrahydrophthalic, and peroxydi-cis-endomethylene-Δ4-tetrahydrophthalic.

  2. 2.

    The thermal decomposition of peroxydiacids in acetic acid obeys a first-order equation with respect to the peroxide. As a result of the decomposition of the peroxydiacids, anhydrides are formed. A mechanism was proposed for their formation by cyclization of acyloxy radicals.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    G. I. Nikishin, E. K. Starostin, B. A. Golovin & E. D. Lubuzh

Authors
  1. G. I. Nikishin
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  2. E. K. Starostin
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  3. B. A. Golovin
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  4. E. D. Lubuzh
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 327–330, February, 1972.

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Nikishin, G.I., Starostin, E.K., Golovin, B.A. et al. Thermal decomposition of cyclic peroxydiacids. Russ Chem Bull 21, 280–283 (1972). https://doi.org/10.1007/BF00857785

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  • DOI: https://doi.org/10.1007/BF00857785

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