Polymer Mechanics

, Volume 9, Issue 6, pp 860–866 | Cite as

Mechanism of the increase in strength and heat resistance of oriented polymeric materials modified by graft copolymerization with vinyl monomers

  • A. I. Kurilenko
Article

Abstract

The mechanical properties and structures of oriented films and fibers composed of polyethylene, polymethyl methacrylate, and other amorphous and crystalline polymers modified by the synthesis of uniformly distributed graft and block copolymers of methyl methacrylate, acrylonitrile, vinylidene chloride and other monomers have been the subject of a comparative investigation. The effect of the grafted polymers on the molecular mobility, relaxation processes, and solubility of the materials is explained by reference to a universal physical "crosslinking" mechanism. A theory of the interrelation between the structure and physical properties of the materials, the nature of the polymers, and the grafting conditions is developed and used to analyze the experimental data on a broad range of systems.

Keywords

Polymer Polyethylene Vinyl Methacrylate Polymethyl Methacrylate 

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Copyright information

© Plenum Publishing Corporation 1975

Authors and Affiliations

  • A. I. Kurilenko

There are no affiliations available

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