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Study of the dimethyl ester of nitromalonic acid and some of its derivatives by the NMR method on13C and14N nuclei

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The data of the13C and14N NMR spectra testify to the strong delocalization of the charge in the anion of the dimethyl ester of nitromalonic acid, and to the averaging of the NO bonds in the trimethylsilyl ether of biscarbomethoxymethanenitronic acid.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    É. T. Lippmaa, M. Ya. Myagi, M. V. Kashutina, S. L. Ioffe & V. A. Tartakovskii

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  1. É. T. Lippmaa
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  2. M. Ya. Myagi
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  3. M. V. Kashutina
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  4. S. L. Ioffe
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  5. V. A. Tartakovskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 188–190, January, 1972.

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Lippmaa, É.T., Myagi, M.Y., Kashutina, M.V. et al. Study of the dimethyl ester of nitromalonic acid and some of its derivatives by the NMR method on13C and14N nuclei. Russ Chem Bull 21, 182–183 (1972). https://doi.org/10.1007/BF00855689

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  • DOI: https://doi.org/10.1007/BF00855689

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