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Substantiation of the method of an “ideal adsorption solution” for calculating the adsorption of binary vapor mixtures from the individual isotherms

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

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Substantiation was offered for the method of an “ideal adsorption solution,” which was proposed by Myers and Prausnitz to calculate the adsorption equilibrium of binary vapor mixtures with a solid adsorbent from the individual isotherms, for the particular case of adsorption systems for which is fulfilled the condition of an affinity of the adsorption isotherms of the vapor mixtures at a constant composition of the adsorption solution, and the condition of the additivity of the affinity coefficient of such a solution.

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Literature cited

  1. A. L. Myers and J. M. Prausnitz, Amer. Inst. Chem. Eng. J.,11, No. 11, No. 1, 121 (1965).

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  2. B. P. Bering and V. V. Serpinskii, Izv. Akad. Nauk SSSR, Ser. Khim., 169 (1972).

  3. B. P. Bering and V. V. Serpinskii, Izv. Akad. Nauk SSSR, Ser. Khim., 166 (1972).

  4. K. M. Nikolaev and M. M. Dubinin, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 1165 (1958).

  5. M. M. Dubinin, Supplement to: Adsorption of Gases and Vapors [Russian translation], IL, Moscow (1948).

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Authors and Affiliations

  1. Institute of Physical Chemistry, Academy of Sciences of the USSR, USSR

    B. P. Bering & V. V. Serpinskii

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  1. B. P. Bering
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  2. V. V. Serpinskii
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Translated from Izvestiya Akademii Nauk SSSR, Seriya, Khimicheskaya, No. 1, pp. 171–173, January, 1972.

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Bering, B.P., Serpinskii, V.V. Substantiation of the method of an “ideal adsorption solution” for calculating the adsorption of binary vapor mixtures from the individual isotherms. Russ Chem Bull 21, 158–160 (1972). https://doi.org/10.1007/BF00855679

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  • DOI: https://doi.org/10.1007/BF00855679

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