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Calculation of adsorption equilibrium of binary vapor mixtures for the case of affined isotherms

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A method was discussed for calculating the values of the integral of the Biggs adsorption equation over the entire range of changes in the adsorption values of the components for the particular case where the condition of the affinity of the adsorption isotherms of binary vapor mixtures at a constant composition of the adsorption phase, and the condition of the additivity of the affinity coefficient of the adsorption solution, are fulfilled.

  2. 2.

    When the indicated conditions are fulfilled the method makes it possible to calculate the adsorption equilibrium of a binary vapor mixture on a solid adsorbent from two individual adsorption isotherms, without making use of the hypothesis of the ideality of adsorption solutions.

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Literature cited

  1. B. P. Bering and V. V. Serpinskii, Izv. Akad. Nauk SSSR, Ser. Khim., 166 (1972).

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Authors and Affiliations

  1. Institute of Physical Chemistry, Academy of Sciences of the USSR, USSR

    B. P. Bering & V. V. Serpinskii

Authors
  1. B. P. Bering
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  2. V. V. Serpinskii
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 169–171, January, 1972.

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Bering, B.P., Serpinskii, V.V. Calculation of adsorption equilibrium of binary vapor mixtures for the case of affined isotherms. Russ Chem Bull 21, 155–157 (1972). https://doi.org/10.1007/BF00855678

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  • DOI: https://doi.org/10.1007/BF00855678

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