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Exchange reactions of group IVB organometallic compounds with bis(allylpalladium chloride)

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Employing the differential thermal analysis method it was established that the reactions of tetraisoamyltin, tetraphenyllead and tetraphenyltin with bis(allylpalladium chloride) respectively proceed at 100, 80 and 120°, and are accompanied by a strong exothermic effect. These temperatures are substantially lower than the decomposition temperatures of the pure organometallic compounds (OMC). The tetraalkyl (aryl) derivatives of silicon and germanium do not react with bis(allylpalladium chloride).

  2. 2.

    The main direction of the reaction: R4M+(AllPdCl)2 is exchange of the radicals of the OMC of the Group IVB elements, R4M, by the chloride of (AllPdCl)2, as a result of which are formed organometal chlorides, R3MCl, and unstable organopalladium compounds of the RPdAll type, which undergo exothermic decomposition under the reaction conditions.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemistry, Academy of Sciences of the USSR, USSR

    G. A. Domrachev, K. G. Shal'nova & V. A. Varyukhin

Authors
  1. G. A. Domrachev
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  2. K. G. Shal'nova
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  3. V. A. Varyukhin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 158–161, January, 1972.

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Domrachev, G.A., Shal'nova, K.G. & Varyukhin, V.A. Exchange reactions of group IVB organometallic compounds with bis(allylpalladium chloride). Russ Chem Bull 21, 143–145 (1972). https://doi.org/10.1007/BF00855674

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  • DOI: https://doi.org/10.1007/BF00855674

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