Conclusions
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1.
A study was made of the reaction of the acid chlorides of acetic, butyric and isobutyric acids with the amide of diethylphosphoric acid, and of the acid chloride of diethylphosphoric acid with the amides of acetic, butyric and benzoic acids and with formanilide.
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2.
With the amide of diethylphosphoric acid the reaction proceeds with the formation of acylamidophosphates, while with the amides of acetic, butyric and benzoic acids and with formanilide the reaction goes with the formation of the ethyl ester of pyrophosphoric acid and the corresponding cyanides or phenyl isocyanide.
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Literature cited
P. I. Alimov and L. N. Levkova, Izv. Akad. Nauk SSSR, Ser. Khim., 1801 (1964).
P. I. Alimov and L. A. Antokhina, USSR Patent 222358 (1967); Byull. Izobr., No. 23, 12 (1968).
Dictionary of Organic Compounds [Russian translation], Vol. 1, IL (1949), p. 14.
Dictionary of Organic Compounds [Russian translation], Vol. 1, IL (1949), p. 373; Beilstein, Handbuch der Organische Chemie, Vol. 2, (1920), p. 275.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 147–150, January, 1972.
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Alimov, P.I., Levkova, L.N., Antokhina, L.A. et al. Reaction of acid chlorides with amides of dialkylphosphoric and carboxylic acids. Russ Chem Bull 21, 132–134 (1972). https://doi.org/10.1007/BF00855671
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DOI: https://doi.org/10.1007/BF00855671