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Fluorine-containingβ-sultones

Communication 38. α-Nitrosotetrafluoroethanesulfonyl fluorid

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    α-Nitrosotetrafluoroethanesulfonyl fluoride, the first member of the geminal nitrosulfonyl compounds, was obtained by the electrophilic substitution method under basic solvolysis conditions.

  2. 2.

    A study was made of some of the properties ofα-nitrosotetrafluoroethanesulfonyl fluoride and it was shown that the sulfofluoride and nitrosyl groupings are labile.

  3. 3.

    The presence of the bis[tetrafluoro-]-(fluorosulfonyl)ethyl]nitrooxide radical inα-nitrosotetrafluoroethanesulfonyl fluoride was detected by the EPR method.

  4. 4.

    The anion-radicals of a new structural type were recorded in the systems ofα-nitrosotetrafluoroethanesulfonyl fluoride with various electron-donor compounds. The spectra of the hyperfine structures were obtained and their assignment was made.

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Literature cited

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Authors
  1. G. A. Sokol'skii
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  2. S. S. Dubov
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  3. A. N. Medvedev
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  4. L. I. Ragulin
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  5. F. N. Chelobov
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  6. Yu. M. Shalaginov
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  7. I. L. Knunyants
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No, 1, pp. 129–138, January, 1972.

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Sokol'skii, G.A., Dubov, S.S., Medvedev, A.N. et al. Fluorine-containingβ-sultones. Russ Chem Bull 21, 116–123 (1972). https://doi.org/10.1007/BF00855668

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  • DOI: https://doi.org/10.1007/BF00855668

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