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The use of an additive scheme for calculating the indices of retention in gas-liquid chromatography

Communicaton 2. The possibility of quantitative consideration of the induction effect

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Interaction of the functional groups according to the mechanism of the inductive effect substantially influences the retention ofα, ω-substituted alkanes by stationary phases of different polarity. It causes approximately half the mean square deviations of the experimental values of the indices of retention from those calculated according to an additive scheme.

  2. 2.

    A quantitative consideration of the inductive influence of the substituents in the calculation of the indices of retention using an additive calculation scheme is possible.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    V. V. Keiko, B. V. Prokop'ev, L. P. Kuz'menko, N. A. Kalinina & G. N. Bokova

Authors
  1. V. V. Keiko
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  2. B. V. Prokop'ev
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  3. L. P. Kuz'menko
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  4. N. A. Kalinina
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  5. G. N. Bokova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 111–116, January, 1972.

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Keiko, V.V., Prokop'ev, B.V., Kuz'menko, L.P. et al. The use of an additive scheme for calculating the indices of retention in gas-liquid chromatography. Russ Chem Bull 21, 99–102 (1972). https://doi.org/10.1007/BF00855664

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  • DOI: https://doi.org/10.1007/BF00855664

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