Conclusions
-
1.
Free radicals inγ irradiated glassy aqueous solutions of carbohydrates were investigated by the methods of EPR and optical spectroscopy at 77°K, and theiryields were measured.
-
2.
The optical characteristics of e −capt in these systems were measured.
-
3.
The kinetics of the photochemical reaction of e −capt with radicals was investigated.
Similar content being viewed by others
Literature cited
W. Williams, Proc. Nat. Acad. Sci.,45, 1744 (1959).
R. I. Abraham and D. H. Whiffen, Trans. Faraday Soc.,54, 1291 (1958).
M. P. Votinov, M. A. Khenokh, E. A. Kuzicheva, V. F. Evdokimov, and V. V. Antuf'ev, Transactions of the Second All-Union Conference on Radiation Chemistry [in Russian], Izd-vo AN SSSR (1960), p. 409.
S. Dilli and I. L. Garnett, Nature,198, 985 (1963).
J. Combrisson and J. Uebersfeld, Compt. Rend.,238, 1397 (1954).
H. Ueda, J. Phys. Chem.,67, 2186 (1963).
N. M. Emanuel', V. A. Sharpatyi, M. T. Nadzhimiddinova, L. I. Kudryashov, S. M. Yarovaya, and N. K. Kochetkov, Dokl. Akad. Nauk SSSR,177, 1142 (1967).
M. T. Nadzhimiddinova and V. A. Sharpatyi, Dokl. Akad. Nauk SSSR,180, 909 (1968).
A. K. Pikaev, The Solvated Electron in Radiation Chemistry [in Russian], Nauka (1969).
B. G. Ershov and A. K. Pikaev, Radiation Res. Revs.,2, 1 (1969).
A. P. Terent'ev and V. M. Potanov, Fundamentals of Stereochemistry [in Russian], Khimiya (1964).
I. E. Makarov and B. G. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 530 (1970).
H. Hase, J. Phys. Soc. Japan,24, 589 (1968).
I. E. Makarov, B. G. Ershov, and A. K. Pikaev, Izv. Akad. Nauk SSSR, Ser. Khim., 1697 (1970).
F. S. Dainton, G. A. Salmon, P. Wardman, and U. Zucker, Proc. Second Tihany Symposium on Radiation Chemistry, Budapest, 247 (1967).
F. S. Dainton and G. Gopinatan, Trans. Faraday Soc.,65, 148 (1969).
K. Eiben, Solvatisierte Elektronen in bestrahlten eingefrorenen Losungen, Karlsrube (1964).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 106–111, January, 1972.
Rights and permissions
About this article
Cite this article
Makarov, I.E., Ershov, B.G. & Pikaev, A.K. Electron paramagnetic resonance spectra of irradiated frozen aqueous solutions. Russ Chem Bull 21, 95–98 (1972). https://doi.org/10.1007/BF00855663
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00855663