Skip to main content
SpringerLink
Log in

Reactions of bis (triethylgermyl) mercury with fluorine-containing organomercury compounds

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Exchange reactions of bis (triethylgermyl)mercury with fluorine-containing mercury compounds of the HgX2 or ClHgX type give derivatives of the series (C2H5)3GeHgX [when X=CF3 and CF(CF3)2] or decomposition products of the latter- mercury and (C2H5)3GeX (X=F, C(CF3)3, CHFCO2C2H5, CF2CO2C2H5, CFClCO2C2H5, and (CF3)CO2C2H5).

  2. 2.

    The compounds (C2H5)3GeCF(CF3)2, (C2H5)3GeC(CF3)3, but not (C2H5)3GeCF(CF3)CO2C2H5 readily undergoβ-decomposition, forming triethylfluorogermane.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. L. G. Makarova and A. N. Nesmeyanov, Methods of Heteroorganic Chemistry [in Russian], Nauka, Rtut' (1965).

    Google Scholar 

  2. M. D. Rausch and J. R. Van Wazer, Inorgan. Chem.,3, 769 (1964).

    Google Scholar 

  3. V. T. Bychkov, Dissertation [in Russian], Gor'kii (1966).

  4. D. Seyferth, R. J. Cross, and B. Prokai, J. Organometal Chem.,7, P20 (1967).

    Google Scholar 

  5. A. G. Lee, J. Organometal. Chem.,16, 321 (1969).

    Google Scholar 

  6. K. Nakanisi, Infrared Spectra and Structure of Organic Compounds [Russian translation], Mir, (1965), p. 207.

  7. A. K. Prokof'ev, V. I. Bregadze, and O. Yu. Okhlobystin, Uspekhi Khimii,39, 412 (1970).

    Google Scholar 

  8. B. I. Petrov, V. P. Polishchuk, L. S. German, O. A. Kruglaya, and N. S. Vyazankin, Dokl. Akad. Nauk SSSR,193, 1315 (1970).

    Google Scholar 

  9. N. S. Vyazankin, E. N. Gladyshev, E. A. Arkhangel'skaya, and G. A. Razuvaev, J. Organometal. Chem.,17, 340 (1969).

    Google Scholar 

  10. N. S. Vyazankin, E. N. Gladyshev, E. A. Fedorova, and G. A. Razuvaev, Dokl. Akad. Nauk SSSR,186, 1082 (1969).

    Google Scholar 

  11. J. Knizek, M. Horak, and V. Chvalovsky, Coll. Czechoslov. Chem. Comm.28, 3079 (1963).

    Google Scholar 

  12. G. A. Morano and A. G. MacDiarmid, Inorgan. Nucl. Chem. Letters,5, 621 (1969).

    Google Scholar 

  13. C. R. Better, J. C. Sendra, and G. Urry, Proc. of the 4th Intern. Conference on Organometal. Chem., Bristol, M1 (1969).

  14. N. S. Vyazankin, G. A. Razuvaev, O. A. Kruglaya, and G. S. Semchikova, J. Organometal. Chem.,6, 474 (1966).

    Google Scholar 

  15. B. M. Gladshtein, I. P. Kulyumin, and L. Z. Soborovskii, Zh. Obshch. Khim.,36, 488 (1966).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry, Academy of Sciences of the USSR, USSR

    N. S. Vyazankin, O. A. Kruglaya, B. I. Petrov, L. S. German, V. R. Polishchuk, B. L. Dyatkin, S. R. Sterlin & B. I. Martynov

  2. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    N. S. Vyazankin, O. A. Kruglaya, B. I. Petrov, L. S. German, V. R. Polishchuk, B. L. Dyatkin, S. R. Sterlin & B. I. Martynov

Authors
  1. N. S. Vyazankin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. A. Kruglaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. B. I. Petrov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. S. German
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. R. Polishchuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. B. L. Dyatkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. S. R. Sterlin
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. B. I. Martynov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 85–90, January, 1972.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Vyazankin, N.S., Kruglaya, O.A., Petrov, B.I. et al. Reactions of bis (triethylgermyl) mercury with fluorine-containing organomercury compounds. Russ Chem Bull 21, 76–79 (1972). https://doi.org/10.1007/BF00855659

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00855659

Keywords

Search

Navigation