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Reactions of ketoalcohols with organophosphorus compounds

Communication 6. The reaction of β-ketoalcohols with dichlorides of trivalent phosphorus acids

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of diacetone andβ-acetoethyl alcohols with phenyldichlorophosphine was investigated by the NMR-P31 method.

  2. 2.

    The previously proposed five-step scheme of interaction ofβ-ketoalcohols with dichlorides of trivalent phosphorus acids was confirmed.

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Literature cited

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Academy of Sciences of the USSR, USSR

    F. S. Mukhametov, N. I. Rizpolozhenskii & Yu. Yu. Samitov

Authors
  1. F. S. Mukhametov
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  2. N. I. Rizpolozhenskii
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  3. Yu. Yu. Samitov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 72–78, January, 1972.

The authors are grateful to R. B. Nigmatullin for taking the IR spectra and to E. I. Loginov for taking the NMR-P31 spectra.

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Mukhametov, F.S., Rizpolozhenskii, N.I. & Samitov, Y.Y. Reactions of ketoalcohols with organophosphorus compounds. Russ Chem Bull 21, 64–69 (1972). https://doi.org/10.1007/BF00855657

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  • DOI: https://doi.org/10.1007/BF00855657

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