Skip to main content
Log in

Calculation of the proton affinity of anions of hydroxy acids

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A model was proposed for calculating the proton affinity of polyatomic anions.

  2. 2.

    The proton affinity of the ions OmXO(OH) 1−n− decreases with increasing electronegativity of the atom X and with increasing number of oxygens surrounding the central atom.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. R. Gillespie, J. Chem. Soc., 2537 (1950).

  2. L. Pauling, General Chemistry, San Francisco (1947), p. 394.

  3. R. P. Bell, The Proton in Chemistry, London (1959).

  4. A. Kossiakoff and D. Harker, J. Amer. Chem. Soc.,60, 2047 (1938).

    Google Scholar 

  5. I. E. Ricci, J. Amer. Chem. Soc.,70, 109 (1948).

    Google Scholar 

  6. J. P. Platt, J. Chem. Phys.,18, 932 (1950).

    Google Scholar 

  7. J. R. Platt, Handbuch der Physik, 37/2, S. Flugge, Springer-Verlag, Berlin (1961), p. 240.

    Google Scholar 

  8. W. G. McDuble and T. L. Brown, J. Amer. Chem. Soc.,89, 3111 (1967).

    Google Scholar 

  9. Yu. A. Borisov and N. N. Bulgakov, Izv. Akad. Nauk SSSR, Ser. Khim., 1606 (1971).

  10. Yu. A. Borisov, N. N. Bulgakov, and A. E. Borisov, Izv. Akad. Nauk SSSR, Ser. Khim., 1480 (1969).

  11. I. V. Abarenkov and V. Heine, Philos. Mag.,12, 529 (1965).

    Google Scholar 

  12. P. Gombash, The Many-Particle Problem in Quantum Mechanics [Russian translation], IL (1952).

  13. V. I. Vedeneev, L. V. Gurevich, V. N. Kondrat'ev, V. A. Medvedev, and E. L. Frankevich, Cleavage Energies of Chemical Bonds. Ionization Potentials and Electron Affinity, Handbook [in Russian], Izd-vo AN SSSR (1962).

  14. L. E. Sutton (editor), Tables of Interatomic Distances and Configurations in Molecules and Ions, London (1958).

  15. C. Coulson, Valency [Russian translation], Mir (1965), p. 204.

  16. J. C. Slater, J. Chem. Phys.,41, 3199 (1964).

    Google Scholar 

  17. J. P. Fischer, Trans. Faraday Soc.,64, 1852 (1968).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 18–23, January, 1972.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Borisov, Y.A., Bulgakov, N.N. Calculation of the proton affinity of anions of hydroxy acids. Russ Chem Bull 21, 16–20 (1972). https://doi.org/10.1007/BF00855647

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00855647

Keywords

Navigation