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Influence of certain complexing substances on the rate of extraction of chromium (III) 8-hydroxyquinolate

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A mechanism explaining the rate of extraction when the catalyst is introduced directly before the beginning of the process was proposed. It is suggested that the acceleration of extraction in this case is due to the formation of an activated complex, including both the ligand-catalyst and the reagent, i.e., the complex in which the coordination number of the central ion of the metal is equal to 8.

  2. 2.

    The existence of a relationship between the position of the ligands in the spectrochemical series and their catalytic action on the extraction of chromium (III) 8-hydroxyquinolate was noted.

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Literature cited

  1. O. M. Petrukhin, L. A. Izosenkova, Yu. N. Dubrov, I. N. Marov, and Yu. A. Zolotov, Zh. Neorgan. Khim.,12, 1407 (1967).

    Google Scholar 

  2. V. A. Bodnya, I. P. Alimarin, and T. F. Sedletskaya, Izv. Akad. Nauk SSSR, Ser. Khim., 1192 (1968).

  3. V. E. Mironov, Uspekhi Khimii,35, 1102 (1966).

    Google Scholar 

  4. P. Moore, F. Basolo, and R. G. Pearson, Inorgan. Chem.,5, 223 (1966).

    Google Scholar 

  5. N. E. Nechaeva, N. F. Zorich, and D. P. Zosimovich, Ukr. Khim. Zh.,32 1273 (1966).

    Google Scholar 

  6. V. Holba, M. Dillinger, and G. Gunderlikova, Chem. Zvesti,19, 823 (1964).

    Google Scholar 

  7. K. B. Yatsimirskii, Izv. SO AN SSSR, Ser. Khim.,3, No. 7, 3 (1968).

    Google Scholar 

  8. F. Basolo and R. Johnson, The Chemistry of Coordination Compounds [Russian translation], Mir (1966).

  9. D. Perrin, Organic Analytical Reagents [Russian translation], Mir (1967).

  10. A. A. Greenberg, Introduction to the Chemistry of Complex Compounds [Russian translation], Mir (1966).

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    V. A. Bodnya & I. P. Alimarin

Authors
  1. V. A. Bodnya
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  2. I. P. Alimarin
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 15–18, January 1971.

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Bodnya, V.A., Alimarin, I.P. Influence of certain complexing substances on the rate of extraction of chromium (III) 8-hydroxyquinolate. Russ Chem Bull 21, 13–15 (1972). https://doi.org/10.1007/BF00855646

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  • DOI: https://doi.org/10.1007/BF00855646

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