Advertisement

Mechanism of the oxidation of aldehydes by oxygen

Communication 3. Study of the CoII → CoIII conversion in the catalytic oxidation of acetaldehyde
  • M. G. Vinogradov
  • R. V. Kereselidze
  • G. I. Nikishin
Physical Chemistry
  • 30 Downloads

Conclusions

  1. 1.

    α-Hydroxyethyl peracetate (the adduct of peracetic acid with acetaldehyde) reacts extremely readily with cobalt diacetate, whereupon cobalt is converted to the trivalent state.

     
  2. 2.

    This reaction plays an important role in the catalytic oxidation of acetaldehyde.

     
  3. 3.

    The kinetics of the thermal decomposition ofα-hydroxyethyl peracetate to peracetic acid and acetaldehyde were studied. The rate constants and activation energy of the decomposition were determined.

     

Keywords

Oxidation Oxygen Acetaldehyde Activation Energy Cobalt 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    M. G. Vinogradov, R. V. Kereselidze, and G. I. Nikishin, Izv. Akad. Nauk SSSR, Ser. Khim., 1056 (1970).Google Scholar
  2. 2.
    C. E. H. Bawn and J. B. Williamson, Trans. Faraday Soc.,47, 735 (1951).Google Scholar
  3. 3.
    C. E. H. Bawn, T. P. Hobin, and L. Raphael, Proc. Roy. Soc.,237, 313 (1956).Google Scholar
  4. 4.
    C. E. H. Bawn, and J. B. Williamson, Trans. Faraday Soc.,47, 721 (1951).Google Scholar
  5. 5.
    R. F. Vasil'ev and N. M. Emanuel, Izv. Akad. Nauk SSSR, Otd. Khim., 387 (1956).Google Scholar
  6. 6.
    G. D. Lyubarskii and M. Ya. Kagan, Zh. Fiz. Khimii,6, 536 (1935).Google Scholar
  7. 7.
    B. Phillips, F. C. Frostick, and P. S. Starcher, J. Amer. Chem. Soc.,79, 5982 (1957).Google Scholar
  8. 8.
    S. Havel, Sb. Vedeck. Praci, Vys. Skola Chem.-Technol. Pardubice,2, 137 (1964).Google Scholar
  9. 9.
    R. Zagradnik, Uspekhi Khimii,30, 1296 (1961).Google Scholar
  10. 10.
    M. K. Shchennikova and E. A. Kuz'mina, Trudy po Khimii i Khim. Tekhnologii, Gor'kii, No. 1 (15) (1966), p. 29.Google Scholar
  11. 11.
    E. Koubek and J. O. Edwards, J. Inorg. and Nucl. Chem.,25, 1402 (1963).Google Scholar
  12. 12.
    P. S. Starcher, B. Phillips, and F. C. Frostick, J. Organ. Chem.,26, 3568 (1961).Google Scholar
  13. 13.
    F. P. Dwyer, E. C. Cyarfas, and D. P. Mellor, J. Phys. Chem.,59, 296 (1955).Google Scholar

Copyright information

© Consultants Bureau 1971

Authors and Affiliations

  • M. G. Vinogradov
    • 1
  • R. V. Kereselidze
    • 1
  • G. I. Nikishin
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRUSSR

Personalised recommendations