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Reaction of lithium 1-methyl-o-carborane and lithium 1-methyl-m-carborane with hexafluorobenzene and pentafluorochlorobenzene

  • L. I. Zakharkin
  • V. N. Lebedev
Brief Communications

Conclusions

  1. 1.

    Lithium o-carborane and lithium m-carborane react with C6F6 to give the bis-o- and bis-m-car-borane derivatives RCB10H10CC6F4CB10H10CR, while with C6F5C1 they react to give predominantly the monosubstituted derivatives RCB10H10CC6F4Cl.

     
  2. 2.

    Exchange of the chlorine atom by lithium occurs when butyllithium reacts with RCB1H10CC6F4Cl, with the formation of RCB10H10CC6F4Li.

     

Keywords

Lithium Chlorine Chlorine Atom C6F6 Hexafluorobenzene 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    R. Robson, M. Stacey, R. Stephens, and I. Tatlow, J. Chem. Soc., 4754 (1960).Google Scholar
  2. 2.
    R. Wiles and A. Massey, Tetrahedron Lett., 5137 (1967).Google Scholar
  3. 3.
    R. Fillr, Advan. Fluorine Chem.,6, 155 (1970).Google Scholar
  4. 4.
    J. Bzewer and H. Heaney, Tetrahedron Lett., 4709 (1965).Google Scholar

Copyright information

© Consultants Bureau 1973

Authors and Affiliations

  • L. I. Zakharkin
    • 1
  • V. N. Lebedev
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR

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