Reduction of carbon dioxide by molecular hydrogen in the presence of complexes of the transition metals

  • I. S. Kolornnikov
  • T. S. Lobeeva
  • M. E. Vol'pin
Brief Communications


It was shown that the catalytic synthesis of the methyl ester of formic acid can be accomplished by the reaction of CO2, H2, and CH3OH in the presence of complexes of the transition metals.


Hydrogen Methyl Ester Dioxide Carbon Dioxide 
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Literature cited

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    A. Misono, Y. Uchida, M. Hidai, and T. Kuse, Chem. Commun., 981 (1968).Google Scholar
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    L. S. Pu, A. Yamamoto, and S. Ikeda, J. Am. Chem. Soc.,90, 3896 (1968).Google Scholar
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    I. S. Kolomnikov, T. S. Lobeeva, and M. E. Vol'pin, Izv. Akad. Nauk SSSR, Ser. Khim., 2650 (1970).Google Scholar
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    P. Haynes, L. H. Slaugh, and J. F. Kohnle, Tetrahedron Lett., 365 (1970).Google Scholar

Copyright information

© Consultants Bureau 1973

Authors and Affiliations

  • I. S. Kolornnikov
    • 1
  • T. S. Lobeeva
    • 1
  • M. E. Vol'pin
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR

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