Estimation of the reactivity of aryl radicals by the nitroxide method

  • G. A. Abakumov
  • É. P. Sanaeva
Brief Communications
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Conclusions

  1. 1.

    The relative reactivity of the radicals: C6H 5 . , p-C6H4CH 3 . , p-C6H4OCH 3 . , p-C6H4Br., and p-C6H4·NO 2 . was determined by the method of competing reactions in a toluene-ethylbenzene mixture.

     
  2. 2.

    The selectivity of the aryl radicals is increased when they form π-complexes with naphthalene.

     

Keywords

Naphthalene Nitroxide Relative Reactivity Aryl Radical 

Literature cited

  1. 1.
    G. A. Abakumov, V. K. Cherkasov, and G. A. Eazuvaev, Dokl. Akad. Nauk SSSR,197, 823 (1971).Google Scholar
  2. 2.
    G. A. Razuvaev, G. A. Abakumov, and V. K. Cherkasov, Dokl. Akad. Nauk SSSR,198, 601 (1971).Google Scholar
  3. 3.
    M. Perkins and P. Ward, J. Chem. Soc., B, 395 (1970).Google Scholar
  4. 4.
    E. Bamberger and E. Renauld, Ber.,30, 2278 (1897).Google Scholar

Copyright information

© Consultants Bureau 1973

Authors and Affiliations

  • G. A. Abakumov
    • 1
  • É. P. Sanaeva
    • 1
  1. 1.Institute of ChemistryAcademy of Sciences of the USSRUSSR

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