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Monosaccharides

Communication 26.β-methyl-D-allo-heptopyranoside-4-ulose and syntheses based on it

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The acetonation ofβ-methyl-D-glycero-D-gulo-heptopyranoside gave the 2, 3∶6, 7-di-O-isopro-pylidene derivative, the oxidation of which gives the 4-keto-heptoside.

  2. 2.

    The obtained ketone was used for the stereodirectional insertion of hydroxy and amino groups into the heptosulose molecule, and also for branching the carbon chain.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2298–2304, October, 1972.

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Dmitriev, B.A., Chernyak, A.Y., Chizhov, O.S. et al. Monosaccharides. Russ Chem Bull 21, 2230–2235 (1972). https://doi.org/10.1007/BF00855304

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  • DOI: https://doi.org/10.1007/BF00855304

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