Advertisement

Investigation of the three-dimensional structure of 7,7-dihalo-3∶4-benzo[4,l,0]bicyclo-3-heptenes

  • B. A. Arbuzov
  • A. N. Vereshchagin
  • S. G. Vul'fson
  • É. M. Kharicheva
Physical Chemistry

Conclusions

  1. 1.

    The conformation of an anti-boat was determined for 7, 7-dichloro-and 7, 7-dibromo-3∶4-benzo[4, 1, 0]bicyclo-3-heptenes on the basis of the dipole moments and Kerr constants.

     
  2. 2.

    The three-dimensional structure of compounds of the bicycloheptene series is determined chiefly by electrostatic factors.

     

Keywords

Dipole Moment Kerr Constant Electrostatic Factor Bicycloheptene 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    A. N. Vereshchagin and S. G. Vul'fson, Zh. Strukt. Khim.,9, 1090 (1968).Google Scholar
  2. 2.
    B. A. Arbuzov, L. A. Grozina, and A. N. Vereshchagin, Izv. Akad. Nauk SSSR, Ser. Khim., 2370 (1969).Google Scholar
  3. 3.
    A. N. Vereshchagin, A. P. Anastas'eva, and B. A. Arbuzov, Izv. Akad. Nauk SSSR, Ser. Khim., 995 (1970).Google Scholar
  4. 4.
    B. A. Arbuzov, A. N. Vereshchagin, S. G. Vul'fson, and A. A. Solov'ev, Izv. Akad. Nauk SSSR, Ser. Khim., 1291 (1972).Google Scholar
  5. 5.
    V. A. Naumov and V. M. Bezzubov, Dokl. Akad. Nauk SSSR,171, 634 (1966).Google Scholar
  6. 6.
    A. N. Vereshchagin and S. G. Vul'fson, Teoret. i Éksperim. Khimiya,4, 548 (1968).Google Scholar
  7. 7.
    A. N. Vereshchagin, A. P. Anastas'eva, and S. G. Vul'fson, Izv. Akad. Nauk SSSR, Ser. Khim., 559 (1969).Google Scholar
  8. 8.
    R. J. W. Le Fevre, B. J. Orr, and G. L. D. Ritchie, J. Chem. Soc. B, 273 (1966).Google Scholar
  9. 9.
    I. L. Fabelinskii, The Molecular Scattering of Light [in Russian], Nauka (1965), Appendix 3.Google Scholar
  10. 10.
    O. A. Osipov and V. I. Minkin, Handbook of Dipole Moments [in Russian], Vysshaya Shkola (1965).Google Scholar
  11. 11.
    C. G. Le Fevre and R. J. W. Le Fevre, Physical Methods of Organic Chemistry (A. Weissberger, editor), Vol. 1, New York (1960), Part 3, Chap. 36.Google Scholar
  12. 12.
    B. A. Arbuzov, V. A. Naumov, and L. F. Shatrukov, Dokl. Akad. Nauk SSSR,163, 355 (1965).Google Scholar
  13. 13.
    V. A. Naumov, V. M. Bezzubov, N. M. Zaripov, and V. G. Dashevskii, Zh. Strukt. Khim.,11, 801 (1970).Google Scholar
  14. 14.
    V. A. Naumov and V. M. Bezzubov, Dokl. Akad. Nauk SSSR,186, 599 (1969).Google Scholar
  15. 15.
    G. Reck. Tetrahedron,26, 599 (1970).Google Scholar
  16. 16.
    M. Muhlstadt, H. van Phiet., J. Graefe, and H. Frieschschleder, Tetrahedron,24, 6075 (1968).Google Scholar
  17. 17.
    H. Frieschleder, J. Graefe, H. van Phiet, and M. Muhlstadt, Tetrahedron,25, 2081 (1969).Google Scholar
  18. 18.
    E. L. Eliel, N. L. Allinger, S. J. Angyal, and G. A. Morrison, Conformational Analysis, New York-London-Sydney (1965), p. 450.Google Scholar
  19. 19.
    A. N. Vereshchagin and S. G. Vul'fson, Izv. Akad. Nauk SSSR, Ser. Khim., 1974 (1968).Google Scholar
  20. 20.
    A. N. Vereshchagin and L. A. Grozina, Teoret. i Éksperim. Khimiya,4, 361 (1968).Google Scholar

Copyright information

© Consultants Bureau 1973

Authors and Affiliations

  • B. A. Arbuzov
    • 1
    • 2
  • A. N. Vereshchagin
    • 1
    • 2
  • S. G. Vul'fson
    • 1
    • 2
  • É. M. Kharicheva
    • 1
    • 2
  1. 1.A. E. Arbuzov Institute of Organic and Physical ChemistryAcademy of Sciences of the USSRUSSR
  2. 2.A. A. Zhdanov Leningrad State UniversityUSSR

Personalised recommendations