Skip to main content
Log in

Investigation of the three-dimensional structure of 7,7-dihalo-3∶4-benzo[4,l,0]bicyclo-3-heptenes

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The conformation of an anti-boat was determined for 7, 7-dichloro-and 7, 7-dibromo-3∶4-benzo[4, 1, 0]bicyclo-3-heptenes on the basis of the dipole moments and Kerr constants.

  2. 2.

    The three-dimensional structure of compounds of the bicycloheptene series is determined chiefly by electrostatic factors.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. A. N. Vereshchagin and S. G. Vul'fson, Zh. Strukt. Khim.,9, 1090 (1968).

    Google Scholar 

  2. B. A. Arbuzov, L. A. Grozina, and A. N. Vereshchagin, Izv. Akad. Nauk SSSR, Ser. Khim., 2370 (1969).

  3. A. N. Vereshchagin, A. P. Anastas'eva, and B. A. Arbuzov, Izv. Akad. Nauk SSSR, Ser. Khim., 995 (1970).

  4. B. A. Arbuzov, A. N. Vereshchagin, S. G. Vul'fson, and A. A. Solov'ev, Izv. Akad. Nauk SSSR, Ser. Khim., 1291 (1972).

  5. V. A. Naumov and V. M. Bezzubov, Dokl. Akad. Nauk SSSR,171, 634 (1966).

    Google Scholar 

  6. A. N. Vereshchagin and S. G. Vul'fson, Teoret. i Éksperim. Khimiya,4, 548 (1968).

    Google Scholar 

  7. A. N. Vereshchagin, A. P. Anastas'eva, and S. G. Vul'fson, Izv. Akad. Nauk SSSR, Ser. Khim., 559 (1969).

  8. R. J. W. Le Fevre, B. J. Orr, and G. L. D. Ritchie, J. Chem. Soc. B, 273 (1966).

  9. I. L. Fabelinskii, The Molecular Scattering of Light [in Russian], Nauka (1965), Appendix 3.

  10. O. A. Osipov and V. I. Minkin, Handbook of Dipole Moments [in Russian], Vysshaya Shkola (1965).

  11. C. G. Le Fevre and R. J. W. Le Fevre, Physical Methods of Organic Chemistry (A. Weissberger, editor), Vol. 1, New York (1960), Part 3, Chap. 36.

  12. B. A. Arbuzov, V. A. Naumov, and L. F. Shatrukov, Dokl. Akad. Nauk SSSR,163, 355 (1965).

    Google Scholar 

  13. V. A. Naumov, V. M. Bezzubov, N. M. Zaripov, and V. G. Dashevskii, Zh. Strukt. Khim.,11, 801 (1970).

    Google Scholar 

  14. V. A. Naumov and V. M. Bezzubov, Dokl. Akad. Nauk SSSR,186, 599 (1969).

    Google Scholar 

  15. G. Reck. Tetrahedron,26, 599 (1970).

    Google Scholar 

  16. M. Muhlstadt, H. van Phiet., J. Graefe, and H. Frieschschleder, Tetrahedron,24, 6075 (1968).

    Google Scholar 

  17. H. Frieschleder, J. Graefe, H. van Phiet, and M. Muhlstadt, Tetrahedron,25, 2081 (1969).

    Google Scholar 

  18. E. L. Eliel, N. L. Allinger, S. J. Angyal, and G. A. Morrison, Conformational Analysis, New York-London-Sydney (1965), p. 450.

  19. A. N. Vereshchagin and S. G. Vul'fson, Izv. Akad. Nauk SSSR, Ser. Khim., 1974 (1968).

  20. A. N. Vereshchagin and L. A. Grozina, Teoret. i Éksperim. Khimiya,4, 361 (1968).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimieheskaya, No. 10, pp. 2183–2187, October, 1972.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Arbuzov, B.A., Vereshchagin, A.N., Vul'fson, S.G. et al. Investigation of the three-dimensional structure of 7,7-dihalo-3∶4-benzo[4,l,0]bicyclo-3-heptenes. Russ Chem Bull 21, 2119–2122 (1972). https://doi.org/10.1007/BF00855279

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00855279

Keywords

Navigation