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Diacetylenic monoamines, derivatives of p-diethynylbenzene, and syntheses based on them

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    When taken in excess, p-diethynylbenzene reacts with paraform and secondary amines to give monoamines in high yield.

  2. 2.

    Unsymmetrical di- and triacetylenic diamines were prepared from the monoamines.

  3. 3.

    Benzaldehyde andα-pyridylcarboxaldehyde can be used as the aldehyde components in the Mannich reaction for p-diethynylbenzene and the monoamines.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemical Kinetics and Combustion, Siberian Division of Academy of Sciences of the USSR, USSR

    I. L. Kotlyarevskii, É. K. Andrievskaya & S. A. Moroz

Authors
  1. I. L. Kotlyarevskii
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  2. É. K. Andrievskaya
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  3. S. A. Moroz
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2812–2814, December, 1970.

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Kotlyarevskii, I.L., Andrievskaya, É.K. & Moroz, S.A. Diacetylenic monoamines, derivatives of p-diethynylbenzene, and syntheses based on them. Russ Chem Bull 19, 2648–2650 (1970). https://doi.org/10.1007/BF00854932

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  • DOI: https://doi.org/10.1007/BF00854932

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