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Kinetics and mechanism of the reaction of nitro and halonitro compounds with potassium iodide and other reducing agents

Communication 5. Kinetics of the reaction of fluoronitromethane with potassium iodide

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The kinetics of the denitrification of fluorotrinitromethane to fluorodinitromethane under the action of potassium iodide in 70% ethanol was investigated.

  2. 2.

    The reaction proceeds according to a total second order and is first order with respect to each component.

  3. 3.

    Sulfuric acid and irradiation accelerate the denitrification of fluorotrinitromethane.

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Literature cited

  1. M. Sh. L'vova, V. I. Slovetskii, and A. A. Fainzil'berg, Izv. Akad. Nauk SSSR, Ser. Khim., 649 (1966).

  2. M. Sh. L'vova, V. I. Slovetskii, and A. A. Fainzil'berg, Izv. Akad. Nauk SSSR, Ser. Khim., 76 (1968).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    V. I. Slovetskii, M. Sh. L'vova, A. A. Fainzil'berg & T. I. Chaeva

Authors
  1. V. I. Slovetskii
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  2. M. Sh. L'vova
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  3. A. A. Fainzil'berg
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  4. T. I. Chaeva
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2690–2694, December, 1970.

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Slovetskii, V.I., L'vova, M.S., Fainzil'berg, A.A. et al. Kinetics and mechanism of the reaction of nitro and halonitro compounds with potassium iodide and other reducing agents. Russ Chem Bull 19, 2532–2536 (1970). https://doi.org/10.1007/BF00854904

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  • DOI: https://doi.org/10.1007/BF00854904

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