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Kinetics and mechanism of the reaction of nitro and halonitro compounds with potassium iodide and other reducing agents

Communication 5. Kinetics of the reaction of fluoronitromethane with potassium iodide
  • V. I. Slovetskii
  • M. Sh. L'vova
  • A. A. Fainzil'berg
  • T. I. Chaeva
Physical Chemistry

Conclusions

  1. 1.

    The kinetics of the denitrification of fluorotrinitromethane to fluorodinitromethane under the action of potassium iodide in 70% ethanol was investigated.

     
  2. 2.

    The reaction proceeds according to a total second order and is first order with respect to each component.

     
  3. 3.

    Sulfuric acid and irradiation accelerate the denitrification of fluorotrinitromethane.

     

Keywords

Potassium Sulfuric Acid Iodide Denitrification Potassium Iodide 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
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Copyright information

© Consultants Bureau 1971

Authors and Affiliations

  • V. I. Slovetskii
    • 1
  • M. Sh. L'vova
    • 1
  • A. A. Fainzil'berg
    • 1
  • T. I. Chaeva
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRUSSR

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