Conclusions
In the series diphenylmethane, triphenylmethane, fluorene, the rate constant for reaction with the potassium naphthalene anion-radical increases symbatically with increase in the acidity of the hydrocarbons, but a decrease in the activation energy in the indicated series is not observed here.
Literature cited
I. E. Eisch and W. C. Kaska, J. Org. Chem.,27, 3745 (1962).
M. N. Terekhova, É. S. Petrov, and A. I. Shatenshtein, in: Reactivity of Organic Compounds [in Russian], Vol. 4, Izd. Tartussk. Univ., Tartu (1967), p. 638.
É. S. Petrov, M. I. Belousova, and A. I. Shatenshtein, ibid., Vol. 2, (1965), p. 316.
É. S. Petrov, M. N. Terekhova, and A. I. Shatenshtein, Dokl. Akad. Nauk SSSR,192, 1053 (1970).
S. P. Solodovnikov, Izv. Akad. Nauk SSSR, Ser. Khim., 452 (1971).
K. Bowden, A. F. Cockerill, and J. R. Gilbert, J. Chem. Soc., B, 179 (1970).
S. Bank and B. Bockrath, J. Am. Chem. Soc.,93, 430 (1971).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2106–2107, September, 1972.
Rights and permissions
About this article
Cite this article
Nasirov, R.N., Solodovnikov, S.P. Study of kinetics of reaction of potassium naphthalene anion-radicals with diphenylmethane, triphenylmethane, and fluorene. Russ Chem Bull 21, 2047–2048 (1972). https://doi.org/10.1007/BF00854641
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00854641