Conclusions
-
1.
The dealuminization process, accomplished using acid solutions of low and medium concentration, proceeds with a retention of the starting mordenite structure.
-
2.
The use of concentrated acids, even in the case of low SiO2/Al2O3 ratios, leads to a destruction of the crystalline skeleton of the mordenite.
-
3.
An increase in the degree of dealuminization is preferably achieved by the technique of coupling treatment with dilute acids and intermediate heating of the samples.
Literature cited
I. M. Belen'kaya, M. M. Dubinin, and I. I. Krishtofori, Izv. Akad. Nauk SSSR, Ser. Khim., 2164 (1967).
L. I. Piguzova, E. N. Prokof'eva, M. M. Dubinin, N. R. Bursian, and Yu. A. Shavandin, Kinetika i Kataliz,10, 315 (1969).
W. L. Kranich, Y. H. Ma, L. B. Sand, A. H. Weiss, and I. Zwiebel, The Second Conference on Molecular Sieves, Worcester, Mass. (1970), p. 802.
P. G. Harris and G. W. Brindley, Am. Mineralogist,39, 819 (1954).
B. I. Shikunov, L. I. Lafer, V. I. Yakerson, I. V. Mishin, and A. M. Rubinshtein, Izv. Akad. Nauk SSSR, Ser. Khim., 204 (1972).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2090–2092, September, 1972.
Rights and permissions
About this article
Cite this article
Mishin, I.V., Klyachko-Gurvich, A.L., Ashavskaya, G.A. et al. Effect of acid treatment conditions on optical and structural properties of dealuminized mordenites. Russ Chem Bull 21, 2026–2028 (1972). https://doi.org/10.1007/BF00854633
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00854633