Skip to main content
SpringerLink
Log in

Intramolecular hydrogen 1,5-shift in monodeutero-1,3-cycloheptadienes

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    2-Deutero-1,3-cycloheptadiene (I) was synthesized. Migration of the system of double bonds in (I) occurs at about 160°, which leads to the formation of an equilibrium mixture of monodeuterocycloheptadienes. Establishing the equilibrium concentrations of the monodeuterocycloheptadienes in the mixture is not accompanied by hydrogen exchange between the molecules.

  2. 2.

    The 1,5-shift of hydrogen in the 1,3-cycloheptadienes proceeds by an intramolecular mechanism.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Literature cited

  1. V. A. Mironov and A. A. Akhrem, Izv. Akad. Nauk SSSR, Ser. Khim., 1641 (1972).

  2. V. A. Mironov and A. A. Akhrem, Izv. Akad. Nauk SSSR, Ser. Khim., 1851 (1972).

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    V. A. Mironov, O. S. Chizhov, Ya. M. Kimel'fel'd & A. A. Akhrem

  2. The Commission on Spectroscopy, Academy of Sciences of the USSR, USSR

    V. A. Mironov, O. S. Chizhov, Ya. M. Kimel'fel'd & A. A. Akhrem

Authors
  1. V. A. Mironov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. S. Chizhov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ya. M. Kimel'fel'd
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. A. Akhrem
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2084–2086, September, 1972.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mironov, V.A., Chizhov, O.S., Kimel'fel'd, Y.M. et al. Intramolecular hydrogen 1,5-shift in monodeutero-1,3-cycloheptadienes. Russ Chem Bull 21, 2019–2021 (1972). https://doi.org/10.1007/BF00854630

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00854630

Keywords

Search

Navigation