Conclusions
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1.
A study was made of the possibility of synthesizing chelate sorbents by the chloromethylation of styrene-divinylbenzene copolymers, followed by their amination with aminoazo compounds that contain various functional groupings that can be used for analytical purposes. The degree of chlorine replacement during amination is 0.4–2.5%.
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2.
The capacity of the sorbents, obtained from copolymers of different structure, was determined for copper and lanthanum. The resins, obtained from copolymers with a macroporous structure, have the maximum exchange capacity.
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3.
The resins can be used for the concentration and separation of microgram amounts of the elements.
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Literature cited
E. B. Trostyanskaya and G. Z. Nefedova, Zh. Analit. Khim.,20, 775 (1965).
G. V. Kharitonova and L. P. Belikova, Vysokomolekul. Soed.,A11, 2424 (1969).
G. Schmuckler, Talanta,12, 281 (1965).
R. F. Hirsh, H. Gancher, and F. R. Russo, Talanta,17, 483 (1970).
S. B. Savvin, Organic Reagents of the Arsenazo III Group [in Russian], Atomizdat (1971), p. 62.
R. Haring, Chelate-Forming Ion-Exchangers [Russian translation], Mir (1971).
G. V. Myasoedova, O. P. Eliseeva, and S. B. Savvin, Zh. Analit. Khim.,26, 2172 (1971).
S. B. Savvin, O. P. Eliseeva, and Yu. G. Rozovskii, Dokl. Akad. Nauk SSSR,180, 374 (1968).
O. P. Eliseeva, S. B. Savvin, and R. F. Gracheva, Zh. Analit. Khim.,25, 45 (1970).
G. V. Myasoedova, L. I. Vol'shakova, and S. B. Savvin, Zh. Analit. Khim.,26, 2081 (1971).
B. N. Laskorin and P. G. Ionisiani, Ion-Exchange Sorbents in Industry [in Russian], Izd. AN SSSR (1963), p. 21.
I. P. Losev and O. Ya. Fedotova, Practical Guide on the Chemistry of High-Molecular Compounds [in Russian], Goskhimizdat (1962), p. 86.
V. I. Kuznetsov and A. A. Nemodruk, Zh. Obshch. Khim.,26, 3285 (1956).
O. P. Eliseeva, Dissertation [in Russian], Moscow (1969), p. 52.
S. V. Rogozhin, V. A. Davankov, and V. V. Korshak, Vysokomolekul. Soed.,A10, 1283 (1968).
A. V. Nikolaev, I. N. Gribanova, I. D. Khol'kina, and N. I. Yakovleva, Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim.,7, No. 3, 91 (1967).
A. N. Popov, Yu. S. Kononov, and M. K. Makarov, Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim.,2, No. 3, 50 (1966).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2033–2036, September, 1972.
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Myasoedova, G.V., Bol'shakova, L.I. & Savvin, S.B. Synthesis of chelate resins from chloromethylated styrene copolymers. Russ Chem Bull 21, 1973–1975 (1972). https://doi.org/10.1007/BF00854619
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DOI: https://doi.org/10.1007/BF00854619