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Reaction of isocyanates with schiff bases

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Electron-donor substituents in the p-positions of the aromatic rings in Schiff bases increase the overall addition rate of the benzoyl and trichloroacetyl isocyanates to Schiff bases and shift the reaction toward the formation of 4-membered rings, whereas electron-acceptor substituents shift the reaction toward the formation of oxidiazinone derivatives.

  2. 2.

    Highly polar solvents (dimethyl sulfoxide and SO2) promote the formation of hexahydro-S-triazine-dione derivatives.

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Literature cited

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Authors and Affiliations

  1. V. I. Ul'yanov-Lenin Kazan State University, Kazan

    N. N. Zobova, G. N. Rusanov & B. A. Arbuzov

Authors
  1. N. N. Zobova
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  2. G. N. Rusanov
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  3. B. A. Arbuzov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2016–2020, September, 1972.

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Zobova, N.N., Rusanov, G.N. & Arbuzov, B.A. Reaction of isocyanates with schiff bases. Russ Chem Bull 21, 1957–1960 (1972). https://doi.org/10.1007/BF00854615

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  • DOI: https://doi.org/10.1007/BF00854615

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