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Selective inhibition of some radical reactions by iron carbonyls

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    In the radical telomerization of deuterium-substituted vinyl chlorides with CBrCl3 accompanied by cis-trans isomerization of the starting deuterovinyl chlorides, it was found that the isomerization is selectively inhibited by Fe(CO)5 and Fe2(CO)9.

  2. 2.

    α,β-d2-Vinyl chloride (ratio of trans/cis isomers=2.5–3.3/1) was synthesized by the addition of HCl to dideuteroacetylene in the presence of HgCl2.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    R. Kh. Freidlina, A. E. Zolotarev, V. I. Dostovalova & B. A. Énglin

Authors
  1. R. Kh. Freidlina
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  2. A. E. Zolotarev
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  3. V. I. Dostovalova
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  4. B. A. Énglin
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2005–2009, September, 1972.

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Freidlina, R.K., Zolotarev, A.E., Dostovalova, V.I. et al. Selective inhibition of some radical reactions by iron carbonyls. Russ Chem Bull 21, 1946–1950 (1972). https://doi.org/10.1007/BF00854612

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  • DOI: https://doi.org/10.1007/BF00854612

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