Conclusions
α,β-Unsaturated aldehydes (furylacrolein, crotonaldehyde, cinnamaldehyde, citral) are quantitatively hydrogenated to the corresponding unsaturated alcohols in the presence of iridium catalyst. The hydrogenation of acrolein gives a mixture of products, containing mainly allyl alcohol.
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V. V. Abalyaeva, A. S. Astakhova, É. N. Bakhanova, and M. L. Khidekel', Izv. Akad. Nauk SSSR, Ser. Khim., 89 (1969).
A. S. Astakhova and M. L.Khidekel', USSR Patent 232966 (1967); Byull. Izobr.,No. 2 (1969); M. L. Khidekel', É. N. Bakhanova, A. S. Astakhova, Kh. A. Brikenshtein, and V. I. Savchenko, USSR Patent 264352 (1968); Byull. Izobr., No. 9 (1970).
A. A. Ponomarev and A. S. Chegolya, Dokl. Akad. Nauk SSSR,145, 812 (1962).
V. I. Gorshkov, Dissertation [in Russian], Moscow (1960).
P. N. Rylander and D. R. Steele, Tetrahedron Lett., 1579 (1969).
P. N. Rylander, N. Himelstein, and M. Kilroy, Engelhard Ind., Techn. Bull.,4, 49 (1963).
K. Hotta and T. Kubomatsu, Bull. Chem. Soc. Japan,42, 1447 (1969).
Dutch Patent 6611392 (1967); Chem. Abstr.,67, 53890E (1967).
C. W. Smith, Acrolein, AP (1962).
M. L. Khidekel', É.N. Bakhanova, A. S. Astakhova, Kh. A. Brikenshtein, V. I. Savchenko, I. S. Monakhova, and V. G. Dorokhov, Izv. Akad. Nauk SSSR, Ser. Khim., 499 (1970).
R. Paul, P. Buisson, and N. Joseph, Compt. Rend.,232, 627 (1951).
D. V. Sokol'skii, Hydrogenation in Solutions [in Russian], Izd. AN KazSSR, Alma-Ata (1962).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1993–1998, September 1972.
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Bakhanova, É.N., Astakhova, A.S., Brikenshtein, K.A. et al. Selective hydrogenation of carbonyl group ofα,β-unsatueated aldehydes in the presence of iridium catalyst. Russ Chem Bull 21, 1934–1938 (1972). https://doi.org/10.1007/BF00854609
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DOI: https://doi.org/10.1007/BF00854609