Conclusions
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1.
The formation and structure of primary and secondary unstable anion radicals was established by the ESR method in the electrochemical reduction of derivatives of nitrophenylhydrazines. The delocalization of the unpaired electron in the anion radicals was studied.
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2.
A quantum chemical calculation of the distribution of spin density in these anion radicals was performed.
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A. A. Vafina, A. V. Il'yasov, I. D. Morozova, I. M. Skrebkova, and Yu. P. Kitaev, Izv. Akad. Nauk SSSR, Ser. Khim., 1731 (1972).
A. V. Il'yasov, Yu. M. Kargin, N. N. Sotnikova, V. Z. Kondranina, B. V. Mel'nikov, and A. A. Vafina, Izv. Akad. Nauk SSSR, Ser. Khim., 932 (1971).
A. H. Maki and D. H. Geske, J. Amer. Chem. Soc.,83, 1852 (1961).
A. V. Il'yasov, Yu. M. Kargin, Ya. A. Levin, I. D. Morozova, N. N. Sotnikova, V. Kh. Ivanova, and R. T. Safin, Izv. Akad. Nauk SSSR, Ser. Khim., 736, 740 (1968).
Atlas of ESR Spectra [in Russian], Izd-vo AN SSSR (1962).
T. Fujinada, Y. Degychi, and K. Umemoto, Bull. Chem. Soc. Japan,37, 822 (1964).
P. Peterson, A. K. Carpenter, and R. F. Nelson, J. Electroanal. Chern.,27, 1 (1970).
A. V. Il'yasov, Yu. M. Kargin, Ya. A. Levin, and N. N. Sotnikova, Summaries of Reports at the All-Union Anniversary Conference on Paramagnetic Resonance [in Russian], Kazan' (1969).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1943–1947, September, 1972.
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Vafina, A.A., Il'yasov, A.V., Morozova, I.D. et al. Investigation by the esr method of certain peculiarities of the reduction of nitrophenylhydrazines. Russ Chem Bull 21, 1886–1889 (1972). https://doi.org/10.1007/BF00854598
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DOI: https://doi.org/10.1007/BF00854598