Skip to main content
Log in

Kinetics of the aquation of tetrachloro- and tetrabromopalladate anions

  • Brief Communications
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The kinetics of the one-step aquation of tetrachloro- and tetrabromopalladate anions in aqueous solutions were studied.

  2. 2.

    The rate constants for the forward and reverse reactions at 25–45° were found, and the activation parameters were determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Literature cited

  1. F. Basolo and R. Pearson, Mechanisms of Inorganic Reactions [Russian translation], Mir (1971), p. 362.

  2. L. Cattalini, Inorganic Reaction Mechanisms, Interscience Publ. (1970), p.263.

  3. M. Eigen, Disc. Faraday Soc.,17, 194 (1954).

    Google Scholar 

  4. Synthesis of Complexes of Metals of the Platinum Group [in Russian]; Nauka (1964), pp. 173 and 176.

  5. G. Czerlinski and M. Eigen, Z. Elektrochem.,63, 652 (1959).

    Google Scholar 

  6. G. Czerlinski, Rev. Sci. Instr.,33, 1184 (1962).

    Google Scholar 

  7. S. M. Smirnov and P. V. Terent'ev, High-Voltage Pulse Generators [in Russian], Énergiya (1964).

  8. F. Basolo, H. B. Gray, and R. G. Pearson, J. Amer. Chem. Soc.,82, 4200 (1960).

    Google Scholar 

  9. M. A. Tucker, C. B. Colvin, and D. S. Martin, J. Morgan. Chem.,3, 1373 (1964).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1426–1428, June, 1972.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Vargaftik, M.N., Igoshin, V.A. & Syrkin, Y.K. Kinetics of the aquation of tetrachloro- and tetrabromopalladate anions. Russ Chem Bull 21, 1380–1382 (1972). https://doi.org/10.1007/BF00854573

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00854573

Keywords

Navigation