Conclusions
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1.
The kinetics of the one-step aquation of tetrachloro- and tetrabromopalladate anions in aqueous solutions were studied.
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2.
The rate constants for the forward and reverse reactions at 25–45° were found, and the activation parameters were determined.
Literature cited
F. Basolo and R. Pearson, Mechanisms of Inorganic Reactions [Russian translation], Mir (1971), p. 362.
L. Cattalini, Inorganic Reaction Mechanisms, Interscience Publ. (1970), p.263.
M. Eigen, Disc. Faraday Soc.,17, 194 (1954).
Synthesis of Complexes of Metals of the Platinum Group [in Russian]; Nauka (1964), pp. 173 and 176.
G. Czerlinski and M. Eigen, Z. Elektrochem.,63, 652 (1959).
G. Czerlinski, Rev. Sci. Instr.,33, 1184 (1962).
S. M. Smirnov and P. V. Terent'ev, High-Voltage Pulse Generators [in Russian], Énergiya (1964).
F. Basolo, H. B. Gray, and R. G. Pearson, J. Amer. Chem. Soc.,82, 4200 (1960).
M. A. Tucker, C. B. Colvin, and D. S. Martin, J. Morgan. Chem.,3, 1373 (1964).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1426–1428, June, 1972.
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Vargaftik, M.N., Igoshin, V.A. & Syrkin, Y.K. Kinetics of the aquation of tetrachloro- and tetrabromopalladate anions. Russ Chem Bull 21, 1380–1382 (1972). https://doi.org/10.1007/BF00854573
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DOI: https://doi.org/10.1007/BF00854573