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Thermodynamics of the interconversions of π-allyl complexes of palladium in aqueous solutions

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The dependence of the optical densities of aqueous solutions ofπ -allylpalladium chloride on temperature was studied spectrophotometrically.

  2. 2.

    On the basis of the results obtained, the enthalpies and entropies for the interconversion of the various forms of theπ -allyl derivative of palladium in aqueous solution were determined.

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Literature cited

  1. L. A. Katsman, M. N. Vargaftik, A. P. Belov, and Ya. K. Syrkin, Izv. Akad. Nauk SSSR, Ser. Khim., 1091 (1971).

  2. N. G. Satsko, A. P. Belov, I. I. Moiseev, and Ya. K. Syrkin, Izv. Akad. Nauk SSSR, Ser. Khim., 2591 (1971).

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Authors and Affiliations

  1. M. V. Lomonosov Institute of Fine Chemical Technology, USSR

    L. A. Katsman, M. N. Vargaftik & Ya. K. Syrkin

Authors
  1. L. A. Katsman
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  2. M. N. Vargaftik
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  3. Ya. K. Syrkin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1424–1425, June, 1972.

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Katsman, L.A., Vargaftik, M.N. & Syrkin, Y.K. Thermodynamics of the interconversions of π-allyl complexes of palladium in aqueous solutions. Russ Chem Bull 21, 1378–1379 (1972). https://doi.org/10.1007/BF00854572

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  • DOI: https://doi.org/10.1007/BF00854572

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