Conclusions
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1.
The reduced chlorodimethylsulfoxide complexes of Pd and Rh catalyze the hydrogenation of allylbenzene and its polymerization to transpropenylbenzene. Dimethyl sulfoxide is not reduced in the presence of allylbenzene.
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2.
The Rh complex catalyzes primarily the isomerization of allylbenzene, while the Pd complex primarily catalyzes its hydrogenation.
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Literature cited
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1422–1424, June, 1972.
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Nazarova, N.M., Freidlin, L.K., Kopyttsev, Y.A. et al. Study of the hydrogenation and isomerization of allylbenzene catalyzed by chlorodimethylsulfoxide complexes of palladium and rhodium. Russ Chem Bull 21, 1376–1377 (1972). https://doi.org/10.1007/BF00854571
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DOI: https://doi.org/10.1007/BF00854571