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Effect of the electronic structure of a chelate ligand on the character of the metal-ligand bond

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The character of the σ-MO Cu-ligand bond in copper complexes depends both on the nature of the atoms which directly constitute the coordination sphere and on the far-removed chelate atoms.

  2. 2.

    The σ molecular orbitals are more covalent if the electronegativity of the directly coordinated atoms is lower.

  3. 3.

    The σ molecular orbitals are more covalent in compounds in which the nearest coordination sphere remains the same if the electronegativity of the remote atoms in the ligand is increased.

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Literature cited

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, USSR

    G. M. Larin & M. E. Dyatkina

Authors
  1. G. M. Larin
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  2. M. E. Dyatkina
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1413–1414, June, 1972.

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Larin, G.M., Dyatkina, M.E. Effect of the electronic structure of a chelate ligand on the character of the metal-ligand bond. Russ Chem Bull 21, 1364–1365 (1972). https://doi.org/10.1007/BF00854566

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  • DOI: https://doi.org/10.1007/BF00854566

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