Conclusions
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1.
A new method is proposed for the synthesis of copolymers of vinyl monomers with acids of the acrylic series; it is based on the use of the “silylation-desilylation” principle, viz., silylation of the carboxyl groups in the monomeric acids, and desilylation of the side-chain, silicon-containing ester groups in the copolymers.
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2.
Carboxyl-containing styrene-methyl methacrylate copolymers with various percentages of unsaturated acid links were synthesized in high yields.
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Literature cited
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1411–1413, June, 1972.
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Andreev, D.N., Asinovskaya, D.N. & Solovskaya, N.A. Synthesis of copolymers with carboxyl groups in the side chains using the “silylation-desilylation” principle. Russ Chem Bull 21, 1361–1363 (1972). https://doi.org/10.1007/BF00854565
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DOI: https://doi.org/10.1007/BF00854565