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Standardless gas-chromatographic analysis method for homologous series of mercaptans, sulfides and disulfides

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A thermodynamic estimate was made of the selectivity of 11 stationary phases for the separation of organosulfur compounds.

  2. 2.

    The following system of columns was selected on the basis of the difference in the values of the free energies of mixing: Apiezon M, poly(ethylene glycols) 1000 and 20,000, and Triton X-305, and also the optimum analysis temperatures of 60 and 130°, for the separation of mixtures of compounds of three homologous series: n-mercaptans, and symmetrical n-sulfides and n-disulfides, in the presence of certain isomeric and cyclic sulfur-containing compounds.

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    R. V. Golovnya & Yu. N. Arsen'ev

Authors
  1. R. V. Golovnya
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  2. Yu. N. Arsen'ev
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1402–1404, June, 1972.

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Golovnya, R.V., Arsen'ev, Y.N. Standardless gas-chromatographic analysis method for homologous series of mercaptans, sulfides and disulfides. Russ Chem Bull 21, 1350–1352 (1972). https://doi.org/10.1007/BF00854561

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  • DOI: https://doi.org/10.1007/BF00854561

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